Let us prove that if $\mathscr{E}$ is a non-zero ideal of $M_{nn}(\mathbb{F})$ then $\mathscr{E}=M_{nn}(\mathbb{F})$:
Let us first show that $\mathscr{E}$ contains at least one invertible matrix: Since $\mathscr{E}\neq \{0\}$, then $\mathscr{E}$ contains at least one non-zero matrix. Let it be $A$, and let $x\in\mathbb{F}$, $x\neq 0$ a non-zero element of $A$ in the $(i,j)$ entry. If we denote by $e_{kl}$ the matrix having $1$ in the $(k,l)$ entry and $0$ everywhere else, then it is easy to show that the matrix
$$e_{ki}Ae_{jk}$$
has $x$ in the $(k,k)$ entry and zero everywhere else. By definition $e_{ki}Ae_{jk}\in\mathscr{E}$. Let $k=1,2,...,n$, where $n$ is the dimension of the v.s. $V$. Since $\mathscr{E}$ is closed under addition, we can sum
$$E=\Sigma_{k=1}^{n}e_{ki}Ae_{jk}=xI\in\mathscr{E}$$
But $x$ is invertible (since it is an element of a field) and let $x^{-1}$ its inverse. $E\in\mathscr{E}$ and thus $x^{-1}E=I\in\mathscr{E}$. But if an ideal $\mathscr{E}$ contains the unit matrix $I$ then it is equal to the whole ring since for any $S \in M_{nn}(\mathbb{F})$
$$I*S=S*I=S \in \mathscr{E}$$
Thus $$\mathscr{E}=M_{nn}(\mathbb{F})$$
Consequently there are no non-trivial ideals in $M_{nn}(\mathbb{F})$ or equivalently: $M_{nn}(\mathbb{F})$ is a simple ring.