I am reading a book on matrix Lie algebras (Brian Hall's). Corollary 2.30. says that if $G$ is a connected matrix Lie group, then every element $A$ of $G$ can be written in the form
$$A=e^{X_1}e^{X_2}\ldots{}e^{X_m}$$
for some $X_1$,$X_2$$\ldots$$X_m$ in the Lie algebra. Immeadiately after it is stressed that even if $G$ is connected, it is not true that any every element $A$ of $G$ canbe written
$$A=e^{X}$$
where $X$ is a Lie algebra element. My background is on physics, and I have many times seen Lie groups written using ony one exponential with absolute impunity (for example with $SU(2)$). Can anybody tell me when it is true that there is some $X$ Lie algebra element for every $A$ in a Lie group?