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Why $R$-Mod is a small category? There is a way to recognize small categories? For example Grp (i.e. category of all groups) is large because every set can be equiped with a group structure.

Dubious
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For any ring $R$, the category $R$-Mod isn't a small category: for any set $S$ one can form the $R$-module $R^{S}=\{f:S\to R\}$, and $R^S\neq R^T$ for any two distinct sets $S\neq T$ (though of course they may be isomorphic), so there are "at least as many $R$-modules as sets", and so the collection of all $R$-modules is a proper class.

In my experience with categories so far, I've never come across a situation where it wasn't clear from the outset (i.e., using what we already know about whatever the objects of our category are) whether a category was small, whether it was large, or whether it made no difference to the discussion at hand.

Zev Chonoles
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One does not need to invoke the axiom of choice to show that the category of groups is not small. One can merely observe that there is no largest cardinality of a group. (In particular, for any cardinal number, there is a group of larger cardinality.) It is irrelevant whether there is a group of every cardinality.