To be formal, if $V$ is countable, then there exists a map $ f:V \to A $ such that $ A \subseteq \Bbb N$ and $f$ is surjective. In order for this "set" (lets call it $B$) to be uncountable(a finite set has finite power set or set of all subsets), $V$ must have infinite cardinality and $B \subseteq \mathcal PV$ where $\mathcal PV$ denotes the power set of $V$. Also I am assuming the set $\{\{ v,\{v,m\}\}| v,m \in V\}$ is an acceptable element of $B$.
We see really we have just one infinite countable $V$ to worry about, that is $\Bbb Q$ and the set of elements of $\Bbb Q$ used to construct any real number (infinite basis are Cauchy sequences or rationals). Between any two integers we know there is an uncountable number of real numbers. So here we have an example of a infinite basis witch is countable, yet yields an uncountable infinite vector space.
Additionally we see that the real numbers as an infinite vector space are not linearly independent. They are spanned by the rationals and $dim\text{ }\Bbb Q = dim\text{ }\Bbb R$ when viewed as vector spaces, though the cardinality is certainly not the same.