Inspired in turn by user 153012's answer which is similar to my answer in this post, then more generally, for any real $k>1$,
$$\Im\left[\operatorname{Li}_3\left(\frac2k\,\big(1\pm\sqrt{1-k}\big)\right)\right] =\color{red}\mp\frac13\arcsin^3\left(\frac1{\sqrt k}\right)\pm\frac2{\sqrt k}\;{_4F_3}\left(\begin{array}c\tfrac12,\tfrac12,\tfrac12,\tfrac12\\ \tfrac32,\tfrac32,\tfrac32\end{array}\middle|\;\frac1k\right)$$
where the OP's case was just $k=3$.
Edit: Courtesy of Oussama Boussif in his answer here, there is also a broad identity for $\rm{Li}_2(x)$ but for the real part,
$$\Re\left[\rm{Li}_{2}\left(\frac{1}{2}+iq\right)\right]=\frac{{\pi}^{2}}{12}-\frac{1}{8}{\ln{\left(\frac{1+4q^2}{4}\right)}}^{2}-\frac{{\arctan{(2q)}}^{2}}{2}
$$