You would need to extend the acton of $S_3$ on $\{1, 2, 3\}$ to an action of $S_5$ on $\{1, 2, 3\}$, i.e. you would need to extend the identity $\mathrm{id} \colon S_3 \to S_3$ to a group epimorphism $p \colon S_5 \to S_3$. This is not possible.
More generally, there exists no group epimorphism $p \colon S_n \to S_m$ if $n \geq 5$ and $n \neq m > 2$ because then $A_n$ is the only proper nontrivial normal subgroup of $S_n$. We would then have $\ker p = \{1\}$, and contradicting $n \neq m$, or $\ker p = A_n$, contradicting $m \neq 2$, or $\ker p = S_n$, contradicting $m \neq 1$.
PS: As we can see from this argument there are precisely four actions of $S_5$ on $\{1,2,3\}$, classified by the group homomorphisms $p \colon S_5 \to S_3$. The case $\ker p = S_5$ corresponds to the trivial action. If $\ker p = A_5$ then $\mathrm{im} \ p \cong S_2$, so we have three such actions, corresponding to the three transpositions of $S_5$: So we fix any of the three elements and let $S_5$ swap the other two where $A_5$ does nothing.