There is a trivial way, namely $\omega$ and $1$ and the set theoretical operation "the next initial ordinal" which gives us $\omega_1$.
For other operations, we can do the following claim:
Suppose $\ast$ is an ordinal operation such that for $\alpha,\beta$ countable we have $\alpha\ast\beta$ is countable, then every countable ordinal $\gamma$, the $\gamma$-th iteration, $\alpha\ast^\gamma\beta$ is countable.
We need to define exactly what does iterations mean:
- $\alpha\ast^{\gamma+1}\beta=(\alpha\ast^\gamma\beta)\ast\beta$;
- If $\delta$ is a limit ordinal then $\alpha\ast^\delta\beta=\sup\{\alpha\ast^\gamma\beta\mid\gamma\lt\delta\}$.
The proof is by induction over the iterations:
We already assume that if $\alpha$ and $\beta$ are countable then $\alpha\ast\beta$ is countable.
Suppose that for iterations of length $\gamma$ we know that $\alpha\ast^\gamma\beta$ is countable, then $\alpha\ast^{\gamma+1}\beta$ is countable since we apply $\ast$ to two countable ordinals.
If $\delta$ is a limit ordinal, and $\alpha\ast^\gamma\beta$ is countable for all $\gamma<\delta$ then we have that $\alpha\ast^\delta\beta$ is a countable limit of countable ordinals and therefore countable.