Assuming you mean ordered pairs:
Step 1: Choose a subset.
Step 2: Choose a subset from the remaining (unchosen) elements.
If you restrict your attention to the situation in which the first subset has size $m$, there are $\binom{n}{m}$ ways to choose the first subset, and $2^{n-m}$ ways to choose the second given the first. (This assumes that the empty set is allowable.) So, the number you want would be
$$
\sum_{m=0}^{n}\binom{n}{m}2^{n-m}.
$$
How can we simplify this? Well, we can write
$$
\sum_{m=0}^{n}\binom{n}{m}2^{n-m}=2^n\sum_{m=0}^{n}\binom{n}{m}\left(\frac{1}{2}\right)^m=2^n\left(1+\frac{1}{2}\right)^n=3^n.
$$
That might seem surprising; but there's another way we could've gotten it. To every one of your $n$ elements, assign a label $0$, $1$, or $2$. The ones with $0$ are left out; the ones with $1$ occur in the first subset; and the ones labeled $2$ occur in the second subset. This is a bijection which shows that there are as many arrangements as there are functions from $n$ objects to $\{0,1,2\}$, which is also precisely $3^n$.