You’ve clearly made some error in reasoning or calculation. For $n=4$, say, it’s
$$\binom41\frac11-\binom42\frac12+\binom43\frac13-\binom44\frac14=4-3+\frac43-\frac14=\frac{25}{12}\;,$$
and
$$1+\frac12+\frac13+\frac14=\frac{12+6+4+3}{12}=\frac{25}{12}\;,$$
just as it’s supposed to be.
In your induction step you should be trying to prove that
$$\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n+1}k\frac1k=\sum_{k=1}^{n+1}\frac1k\tag{1}$$
from the induction hypothesis that
$$\sum_{k=1}^n(-1)^{k+1}\binom{n}k\frac1k=\sum_{k=1}^n\frac1k\;.\tag{2}$$
The most natural way to try to do this is to add $\frac1{n+1}$ to both sides of $(2)$ and then try to reduce the lefthand side to the lefthand side of $(1)$, i.e., to try to show that
$$\sum_{k=1}^n(-1)^{k+1}\binom{n}k\frac1k+\frac1{n+1}=\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n+1}k\frac1k\;.\tag{3}$$
It would certainly help if the binomial coefficients matched up; this suggests that we should use Pascal’s identity on the righthand side of $(3)$:
$$\begin{align*}
\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n+1}k\frac1k&=\sum_{k=1}^{n+1}(-1)^{k+1}\left(\binom{n}k+\binom{n}{k-1}\right)\frac1k\\
&=\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n}k\frac1k+\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n}{k-1}\frac1k\;.
\end{align*}$$
Thus, we’re trying to prove that
$$\sum_{k=1}^n(-1)^{k+1}\binom{n}k\frac1k+\frac1{n+1}=\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n}k\frac1k+\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n}{k-1}\frac1k\;.\tag{4}$$
The first sum on the righthand side of $(4)$ might as well just run from $k=1$ to $n$, since $\binom{n}{n+1}=0$ anyway. Thus, we can subtract that sum from both sides to find that $(4)$ is equivalent to
$$\frac1{n+1}=\sum_{k=1}^{n+1}(-1)^{k+1}\binom{n}{k-1}\frac1k\;.\tag{5}$$
At this point it’s useful to know that
$$\binom{n}{k-1}\frac1k=\binom{n+1}k\frac1{n+1}\;;$$
I’ll leave that to you to verify. Then an easy application of the binomial theorem will get you what you want.