Hint:
This is a ''canonical '' isomorphism between $\mathbb{C}$ and a subring of $M_2(\mathbb{R})$ (here).
to show this fact the first step is to prove that the set $\mathcal{C}$ of matrices of the form
$$
\begin{bmatrix}
a&b\\
-b&a
\end{bmatrix}
\qquad a,b \in \mathbb{R}
$$
is a field.
The associative and distributive properties of sum and product are inherited by the ring structure of $M_2(\mathbb{R}$, and so the existence of the neutral elements for the two operations. But we have to prove that any element of $\mathcal{C}$ has an inverse and that the product is commutative.
Commutativity is easy verified :
$$
\begin{bmatrix}
a&b\\
-b&a
\end{bmatrix}
\begin{bmatrix}
x&y\\
-y&x
\end{bmatrix}
=
\begin{bmatrix}
ax-by&ay+bx\\
-bx-ay&-by+ax
\end{bmatrix}=
\begin{bmatrix}
x&y\\
-y&x
\end{bmatrix}
\begin{bmatrix}
a&b\\
-b&a
\end{bmatrix}
$$
For the invertibility note that, for $A \in \mathcal{C} $, $\det(A)=a^2+b^2 \ne0 \forall a,b \in \mathbb{R} $
and
$$
\begin{bmatrix}
a&b\\
-b&a
\end{bmatrix}^{-1}=
\dfrac{1}{a^2+b^2}
\begin{bmatrix}
a&-b\\
b&a
\end{bmatrix}
$$
Now (second step) it is easy to see that for the given $\phi$ we have
$$
\phi(1)=\begin{bmatrix}
1&0\\
0&1
\end{bmatrix}
$$
and
$$ \phi(z)=A \Rightarrow \phi(\bar z)=A^T\Rightarrow \phi(z^{-1})=A^{-1}$$
and , obviously, $ \phi(z)=A \Rightarrow \phi(-z)=-A$.
The last step is to show that $ker (\phi)$ is trivial, but this is immediate since
$$
\phi(a+ib)=\begin{bmatrix}
0&0\\
0&0
\end{bmatrix} \iff
a=b=0
$$
Finally: note that there are many (infinite) representations of $\mathbb{C}$ of this type, but is seems that there only two such that $\psi(\bar z)=A^T$ ( see the question: Matrix representation of $\mathbb{C}$ as $^*$Algebra.).