There is an ambiguity in your question. I assume you mean $f(x)$ is continuous everywhere but at $x=0$ and differentiable everywhere but at $x=0$. In this case what you said and the converse of what you said can be violated.
I give you some examples. Consider the following function
$$f(x) = \left\{ \matrix{
{x^2}\sin ({1 \over x})\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x \ne 0 \hfill \cr
0\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x = 0 \hfill \cr} \right.$$
It's derivative is
$$f'(x) = \left\{ \matrix{
2x\sin ({1 \over x})\, - \cos ({1 \over x})\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x \ne 0 \hfill \cr
0\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x = 0 \hfill \cr} \right.$$
You can simply see that $f'(0)$ exist since
$$f'(0) = \mathop {\lim }\limits_{x \to 0} {{f(x) - f(0)} \over {x - 0}} = \mathop {\lim }\limits_{x \to 0} {{f(x)} \over x} = \mathop {\lim }\limits_{x \to 0} {{{x^2}\sin ({1 \over x})} \over x} = \mathop {\lim }\limits_{x \to 0} x\sin ({1 \over x}) = 0$$
but $\mathop {\lim f'(x)}\limits_{x \to 0} $ doesn't exist. Hence, the existence of $f'(0)$ doesn't imply the existence of $\mathop {\lim f'(x)}\limits_{x \to 0} $.
The vice versa can also happen, i.e., $\mathop {\lim f'(x)}\limits_{x \to 0} $ exists but $f'(0)$ doesn't exist. For this case you can consider the following simple function
$$f(x) = \left\{ \matrix{
\sin (x)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x \ne 0 \hfill \cr
1\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,x = 0 \hfill \cr} \right.$$
which is a discontinuous function at $x=0$ and hence $f'(0)$ doesn't exist but simply you can check that $\mathop {\lim f'(x)}\limits_{x \to 0} $ exists.