The best way to obtain rational approximants of $\pi$ is by using continued fractions.
But the simple continued fraction for $\pi$ has no pattern - you will never be able to guess it without knowing the value of $\pi$ first.
So, you can use one of the better, regular continued fractions for $\pi$, like this one:
$$\pi=3+\dfrac{1}{6+\dfrac{3^2}{6+\dfrac{5^2}{6+...}}}$$
It converges much better than simple series, for example:
$$\pi=3+\dfrac{1}{6+\dfrac{3^2}{6+\dfrac{5^2}{6}}}=\frac{1321}{420}=3.14524$$
The next fraction (with $7^2$) looks nicer:
$$\frac{989}{315}=3.13968$$
See here for another three regular fractions for $\pi$.
You can also use infinite products instead of series, because you will immediately get a fraction at every step. Like Wallis product for example:
$$\prod^{\infty}_{n=1}\frac{2n}{2n-1}\frac{2n}{2n+1}=\frac{2}{1}\frac{2}{3}\frac{4}{3}\frac{4}{5}\frac{6}{5}\frac{6}{7}...$$
But it converges very slowly and gives huge fractions, for example:
$$\prod^{20}_{n=1}\frac{2n}{2n-1}\frac{2n}{2n+1}=\frac{151115727451828646838272}{48691767863540419643025}=3.10352$$