In general:
If the base 3 representation of $n$ starts with a $1$, $f(n)$ switches it to $2$;
If the base 3 representation of $n$ starts with a $2$, $f(n)$ switches it to $1$ and multiplies by $3$.
Given this, we simply write $100 = 81 + 9 + 9 + 1 = 10201_3$, so that
$$
f(100) = f(10201_3) = 20201_3 = \boxed{181}.
$$
Proof of this description of $\boldsymbol{f}$
It is clear that $f$, when defined this way, satisfies $f(n+1) > f(n)$ and $f(f(n)) = 3n$ for all $n$. So if you are assuming $f(100)$ is completely determined by these conditions (given the wording of the problem), you can stop here.
Otherwise, we need to prove that the $f$ we defined is the only possible $f$.
So fix any $g$ satisfying $g(g(n)) = 3n$ and $g(n+1) > g(n)$ for all $n$; we will prove that $g(n) = f(n)$ for all $n$, where $f(n)$ is as we defined.
First, note the following: (1) $g$ is surjective onto multiples of three (since $g(g(n)) = 3n$); (2) $g(3n) = g(g(g(n))) = 3g(n)$; (3) $f$ is surjective onto multiples of three; (4) $f(3n) = 3f(n)$; and (5) $f(n+1) - f(n) \in \{1, 3\}$ for all $n \ge 1$.
(3) and (4) are justified by the same reasoning as (1) and (2); (5) is the most important and follows from our definition of $f$, if you do cases on the base $3$ representation of $n$.
We proceed by strong induction. For the base case, as others have observed, $1 < g(1) < 3$ implies $g(1) = 2$ and $g(2) = 3$, i.e. $g(1_3) = 2_3$ and $g(2_3) = 10_3$, so $g$ agrees with $f$.
For the inductive step, fix $k \ge 1$, suppose that $g(i) = f(i)$ for $i \le k+1$, and consider $g(3k), g(3k+1), g(3k+2), g(3k+3)$.
We have $g(3k) = 3g(k) = 3f(k)$, and $g(3k+3) = 3f(k+1)$.
By (5), there are two cases:
If $f(k+1) - f(k) = 1$, for $g$ to be strictly increasing we must pick $g(3k+1) = 3f(k) + 1$, and $g(3k+2) = 3f(k) + 2$.
In particular $g(3k+1) = f(3k+1), g(3k+2) = f(3k+2)$.
If on the other hand $f(k+1) - f(k) = 3$, for $g$ to be surjective onto multiples of $3$ we must pick $g(3k+1) = 3f(k) + 3$, $g(3k+2) = 3f(k) + 6$. In particular $g(3k+1) = f(3k+1), g(3k+2) = f(3k+2)$.
So this completes the induction.