You are misinterpreting 3.2.2(b).
In fact, $\sum\limits_{n=1}^{\infty}\frac{(-1)^n}{n}$ does not converge absolutely, as you note; hence this series also does not converge unconditionally.
Indeed, for the series to converge unconditionally to $a$, it would have to be the case that for every $\epsilon\gt 0$ there is a finite set $J(\epsilon)$ such that for all finite subsets $J$ that contain $J(\epsilon)$ we have that $|a-\sum_{j\in J} a_j|\lt\epsilon$. But in this series, the positive terms diverge (as do the infinite terms). So for every $\epsilon\gt 0$ there is a finite set of even indices for which the sum is as large as we want, and so we can always find finite subsets that are arbitrarily far from any particular real number $a$.
You are also misunderstanding unconditional convergence. It does not reduce to ordinary convergence even when the index set is the positive integers. What makes you think so? Unconditional convergence in the case of sequences essentially tells you that you that given a "degree of tolerance" ($\epsilon$), there is a finite set of terms that account for "most" of the summation, in the sense that the sum of those finitely many terms is within the tolerance of the limit, and no finite number of the remaining terms will get you out of that "tolerance zone." This is different from regular convergence, in which you can only omit a "tail" of the sequence. The example of the alternating harmonic series highlights why this is very different: for any $N\gt 0$, there is always a way to pick finitely many terms "beyond the $N$th term" that add up to a lot, because the tail will take care of this by making the total contribution of the entire "tail" negligible. That is, the entire tail cannot contribute much, but in unconditional convergence no finite subset of the tail is allowed to contribute much. That's a much stronger condition than regular convergence (which makes sense given that it is equivalent to absolute convergence, which is likewise a much stronger condition than regular convergence).