From group axioms, any $x$ in a group commutes with the identity, with itself, and with its inverse. By a "highly noncommutative" group is meant one for which these are the only cases of commuting elements. I found that $S_3$ (permutations of $\{1,2,3\}$) has this property, and am looking for other highly noncommutative finite groups. (Or infinite ones.) The only easy thing I noticed is that such a group should not contain any element $x$ of order greater than $3$ since if so $x$ commutes with $x^2$ and $x^2$ is neither the identity, nor $x$, nor the inverse of $x.$ However I couldn't find any such groups other than $S_3$ [though I may just not be seeing some obvious candidates].
In a comment, user moonlight has considered free products of copies of the integers mod 2 or mod 3, which also seem to me to be examples. [I didn't check all the details for these examples...]
Note: The integers mod $3$ is another example: The only distinct nonidentity elements are $1,2$ and these form an inverse pair ($1+2=0$). Also the integers mod 2 are an example, there not being distinct nonidentity elements to check anyway.