(Partial answer but too long for a comment.) For $k=2$, the expected number of draws required is $2n \ln 2n - cn + o(n)$, where $c=\log4-\gamma\approx 0.809$ (i.e. you have to collect almost all the coupons.) What's happening here is that, as you get close to completing one set of coupons, you tend very strongly to make more progress on the other set. This effect is strongest for $k=2$, but becomes weaker as $k$ increases. As we'll see, the analysis for $k=2$ degenerates in a way which makes it much easier than the general case, but the method should still apply in principle. The following is a sketch:
We have a random walk in an acyclic ranked directed graph. A node is a pair $(a,b)$ indicating we have $a$ coupons remaining to collect in the first set, and $b$ coupons in the second set. We start at $(n,n)$, and move from $(a,b)$ to either $(a-1,b)$ or $(a,b-1)$ with probability $a/(a+b)$ or $b/(a+b)$ respectively. The rank of a node is $a+b$; each move decreases the rank by one. The expected time (number of coupons required) to take one step from node $(a,b)$ is $2n/(a+b)$ (note it depends only on the rank, not the direction). In particular, all paths from the start down to a given rank $a+b$ have the same expected delay, namely
$$2n\left(\frac1{2n}+\frac1{2n-1}+\cdots+\frac1{a+b+1}\right)
=2n(H(2n)-H(a+b)),$$
where $H(k)$ is the $k$-th harmonic number.
What we're interested in is the probability of seeing a transition $(a,1)\to(a,0)$ for various $a>0$; that requires knowing the number of paths from $(n,n)$ to $(a,b)$ (which is $\binom{2n-a-b}{n-a}$) and their probabilities (the probability of a path is the product of the edge probabilities.) It's easy to see that all paths from $(n,n)$ to $(a,b)$ have the same probability $Pr((n,n)\leadsto(a,b))$ (exercise: compute it!). What degenerates in the $k=2$ case is that
$Pr((n,n)\leadsto(a,0))$ is independent of $a$, so we can effectively ignore all the path probabilities, and just count paths.
We find that the expected number of coupons drawn before the first completed set is
$$\frac{2n}{\binom{2n-1}n}\sum_{i=0}^{n-1}\binom{n-1+i}{i}(H(2n)-H(n-i)).$$
After much cajoling, Mathematica tells is this is asymptotically
$$2n\left(H(2n)-\ln4\right)+O(1)=2n(\ln n -(\ln4-\gamma))+O(1),$$
where the final term (haven't worked it out) appears to be less than $1$.
For example, with $n=10$ the exact probability is $526157011/11639628=45.2039$ and $20(H(20)-\ln4)=44.2289$; a Monte Carlo run of $1000$ trials gave $45.09$.