Any polynomial over a field factors completely over its splitting field. For real polynomials, it turns out that adjoining $\sqrt{-1}$ to $\mathbb{R}$ gives the algebraic closure, and so every real polynomial factors over $\mathbb{C}$. So your question's assumption is incorrect.
On the other hand, there are equations using radicals that more or less give the roots of a quadratic, cubic or quartic polynomial over a field of characteristic zero. In some cases these formulae are somewhat silly because it is usually not easier to find the cube-root of a complex number than to find the roots of the original cubic polynomial! It is useless to say that we can use exponentials, trigonometric functions and their inverses, since they also cannot be simplified. If we eventually want to compute an approximation, we do not even want to use the cubic equation! There are root-finding algorithms that work for any arbitrary polynomial over the reals and make formulae using radicals completely redundant in the real world where we do not need infinite precision.
But it is still an interesting question whether there is a general formula for the roots of a quintic polynomial over a field $F$ that only uses radicals, in other words whether the roots are in some radical extension of $F$. It turns out that it is possible exactly when the Galois group of the Galois closure of the field is solvable ("solvable" arose from this very problem of trying to solve polynomials), in other words there is a chain of groups from that group to the trivial group such that the quotient between consecutive groups in the chain is cyclic. So everything reduces to the nature of the Galois group. See https://math.stackexchange.com/a/38901/21820 for an overview of the possible Galois group of an irreducible quintic. I know that for a quartic over the rationals there are easy ways to determine the Galois group just by looking at the coefficients. I do not know if there are deterministic tests for quintics.