I'm preparing (to teach) my first class of undergraduate topology and I'm looking for some elementary, motivating applications of topology for the first day. We'll be following Munkres, starting with point-set topology and then ending the semester with advanced topics such as knot theory or algebraic topology. The students will not have had algebra and this might be the first course they take after introduction to proof.
I'm looking for everyday facts that are easily stated and proved nicely with topology. For instance, I can illustrate Brouwer's fixed point theorem with a map of campus: If I drop the map on the ground, there is some point on the map over the point it represents. If I rip the map into pieces, I can put the map parts all over campus so that no map point is over the point it represents.
Most "applications" that I can think of / are in Real Life Applications of Topology are too advanced for a first, introductory day.