A heuristic is that an integer $n$ is prime with "probability" one in $\ln n$, and so we can estimate the sum with its "expected" value:
$$ \sum_{\substack{p \leq n \\ p \text{ prime}}} \frac{1}{p}
\approx \sum_{k=2}^n \frac{1}{k \ln k} \approx \int_2^n \frac{\mathrm{d}x}{x \ln x} \approx \ln \ln n$$
In fact, the Meissel-Mertens constant is given by
$$ M = \lim_{n \to \infty} \left( \sum_{\substack{p \leq n \\ p \text{ prime}}} \frac{1}{p} - \ln \ln n \right) $$
Another heuristic is that the $n$-th prime is approximately $n \ln n$, so
$$ \sum_{k=1}^n \frac{1}{p_k} \approx \sum_{k=2}^n \frac{1}{k \ln k} \approx \int_2^n \frac{\mathrm{d}x}{x \ln x} \approx \ln \ln n$$
(the lower bound is tweaked to make the sum well-defined; that's okay since the first few terms contribute a fixed value, and so contribute to the total sum in an asymptotically negligible way)
Note that these two heuristics are compatible:
$$ \sum_{k=1}^n \frac{1}{p_k} = \sum_{\substack{p \leq p_n \\ p \text{ prime}}}
\frac{1}{p} \approx \ln \ln p_n \approx \ln \ln (n \ln n)
= \ln(\ln n + \ln \ln n) \approx \ln \ln n$$
so the difference between "the first $n$ prime reciprocals" and "the prime reciprocals for primes less than $n$" is asymptotically negligible. In fact, we can estimate
$$ \sum_{\substack{n \leq p \leq p_n \\ p \text{ prime}}}
\frac{1}{p} \approx \ln \ln p_n - \ln \ln n = \ln \frac{\ln p_n}{\ln n}
\approx \ln \frac{\ln n + \ln \ln n}{\ln n}
\\ = \ln\left(1 + \frac{\ln \ln n}{\ln n}\right) \approx \frac{\ln \ln n}{\ln n}
$$