Note that any isomorphism between two extensions of $\mathbb Q$ must preserve $\mathbb Q$.
This means that an isomorphism of fields between $\mathbb Q[\sqrt 2]$ and $\mathbb Q[\sqrt 3]$ is determined by where $\sqrt 2$ is mapped to.
Suppose that $f$ was such isomorphism then $f(\sqrt 2)^2=f(\sqrt 2^2)=f(2)=2$. However there is no element in $\mathbb Q[\sqrt 3]$ whose square is $2$, therefore there is no isomorphism as fields.
As vector spaces, however, $\mathbb Q[\sqrt 2]$ is spanned by $\{1,\sqrt 2\}$ and similarly $\mathbb Q[\sqrt 3]$ is spanned by $\{1,\sqrt 3\}$ so it is fairly easy to find an isomorphism between those vector spaces.