An important reference is this. Using eq.(3.3) in the paper
$${\rm Li}_2(1-z)=-{\rm Li}_2(z)+\frac{\pi^2}{6}+\ln(1-z)\ln z$$
from the definition
$${\rm Li}_2(z)=\sum_{k=1}^\infty\frac{z^k}{k^2}$$
you will get immediately eq.(3.7) in the paper, the expansion for $z=1$,
$${\rm Li}_2(z)=\frac{\pi^2}{6}-\sum_{k=1}^\infty\frac{(1-z)^k}{k^2}+\ln(1-z)\sum_{k=1}^\infty\frac{z^k}{k}.$$
Remembering that
$$\ln(1+z)=\sum_{n=1}^\infty(-1)^{n+1}\frac{z^n}{n}$$
you will recognize that
$$\ln(1-z)\sum_{k=1}^\infty\frac{z^k}{k}\approx z\ln z$$
while you have to retain just the first term from the other series. Putting all together you get your approximation.