Starting from the axiom of choice and passing the lemma of Zorn we arrive at the well-ordering theorem which states that for every set $X$ there exists a well-ordering with domain $X$.
I am aware that possibly nobody will ever be able to construct an explicit well-ordering of $\mathbb R$. There are in fact enough questions to be found here on math.stackexchange.com
But what about the "next best thing": an explicit (=constructed) well-ordering of $\mathbb Q$?