Suppose that you have an LU - Decomposition of matrix A:
$$
A=LU,
$$
Where U is upper-triangle and L is lower-triangle. Then the original system is:
$$
LUx=b.
$$
Let us break the task into two parts: first, we find $y$ such that
$$
Ly=b.
$$
Then,find x such that
$$
Ux=y.
$$
It is obvious by multiplying the last equation by L from the left that such $x$ will be the solution to the original problem.
Now, what makes LU - decomposition useful is that both sub-tasks can be exactly solved in one pass! (That is, the complexity is $O(n^2)$, where n is the dimensionality of $x$). This is because of the special triangle form of both L and U.
When solving the first system of equations for $y$, you can start from finding $y_1$ - this would be elementary because the first equation will be of the form $L_{11}y_1=b_1$. Then plug this value into the second equation, find $y_2$, and so on. Note that this is equivalent to simple Gaussian elimination when you don't have to do the first (actually, the hardest part) of converting the matrix to the triangular form - it is already triangular. Now, performing the same process for $x$ (but this time you start with $x_n$ and then proceed upwards), you would have the solution in $O(n^2)$).
In practice, though, this trick would be useful only for large matrices (definitely not 3x3) when implementing a numerical solver, because the hardest part of the process is actually finding the LU - decomposition. This procedure is not linear in complexity (refer to the Wikipedia page for some estimates), but this is still easier than $O(n^3)$ for simple Gaussian elimination.
Of course, when solving 3x3 matrices by hand, you better stick with simple Gaussian elimination ;)