We can start with $\sqrt{4-2\sqrt{3}} = a + b\sqrt{3}$ and square both sides. This gives us
$$ 4-2\sqrt{3} = a^2 + 2ab\sqrt{3} + 3b^2 $$
Because $a$ and $b$ are said to be rational, we know that the only term which will be a multiple of $\sqrt{3}$ is $2ab\sqrt{3}$ From this, we can split our system into two equations:
$$ 2ab = -2 $$
and
$$ a^2 + 3b^2 = 4$$
Let's use the first equation to sub $b = -1/a$. This gives us
$$ a^2 + 3/a^2 = 4 \Rightarrow a^4 -4a^2 + 3 = 0 $$
The quadratic formula then gives us $a = 1$ and $a = -1$, which would make $b = -1$ and $b = 1$, respectively. Because $\sqrt{3} > 1$ and the square root is always defined as positive, $\sqrt{4-2\sqrt{3}} = 1 - \sqrt{3}$ is an extraneous solution. Therefor, the only solution is $a = -1$ and $b = 1$.