$0.65$ is the maximum-likelihood estimate, but for the problem you describe, it is too simple. For example, if you toss the coin just once and you get a head, then that same rule would say "prob = 1".
Here's one way to get the answer. The prior density is $f(p) = 1$ for $0\le p\le 1$ (that's the density for the uniform distribution). The likelihood function is $L(p) = \binom{100}{65} p^{65}(1-p)^{35}$. Bayes' theorem says you multiply the prior density by the likelihood and then normalize, to get the posterior density. That tells you the posterior density is
$$
g(p) = \text{constant}\cdot p^{65}(1-p)^{35}.
$$
The "constant" can be found by looking at this. We get
$$
\int_0^1 p^{65} (1-p)^{35} \; dp = \frac{1}{101\binom{100}{65}},
$$
and therefore
$$g(p)=101\binom{100}{65} p^{65}(1-p)^{35}.
$$
The expected value of a random variable with this distribution is the probability that the next outcome is a head. That is
$$
\int_0^1 p\cdot 101\binom{100}{65} p^{65}(1-p)^{35}\;dp.
$$
This can be evaluated by the same method:
$$
101\binom{100}{65} \int_0^1 p\cdot p^{65}(1-p)^{35}\;dp = 101\binom{100}{65} \int_0^1 p^{66}(1-p)^{35}\;dp
$$
$$
= 101\binom{100}{65} \cdot \frac{1}{\binom{101}{66}\cdot 102} = \frac{66}{102} = \frac{11}{17}.
$$
This is an instance of Laplace's rule of succession (Google that term!). Laplace used it to find the probability that the sun will rise tomorrow, given that it's risen every day for the 6000-or-so years the universe has existed.