I suspect that only such ring homomorphisms are identity and conjugation, but I cannot see how any homomorphisms from $\mathbb{C}$ to itself fixes the real axis.
I have shown that $f$ should fix any rational numbers, but I cannot extend this result to irrational numbers. Normally, one would progress by showing that $f$ is actually continuous, and density of $\mathbb{Q}$ then implies the result.
But even if I restrict the domain to $\mathbb{R}$, since the codomain is $\mathbb{C}$, I cannot see how to show this. In fact, I even doubt if it actually is continuous. One certain way would be to show that range of $f$ is $\mathbb{R}$ when restricted to $\mathbb{R}$, but it seems to be impossible for me.
How should I progress?