Assuming "polynomial" means "polynomial in $z$", i.e. of the form $\sum_{k=0}^n a_k z^k$, then no, they are not dense, and the function $\bar{z}$ is not in their uniform closure.
The high-level reason is that polynomials are holomorphic on the unit disk, holomorphic functions are closed under uniform convergence, and $\bar{z}$ is not holomorphic.
For a direct proof, consider the linear functional $I(f) = \int_{S^1} f(z)\,dz = \int_0^{2\pi} f(e^{i\theta}) i e^{i\theta}\,d\theta$. This is clearly continuous with respect to the uniform norm since
$$|I(f)| \le \int_0^{2\pi} |f(e^{i\theta})| |ie^{i\theta}|\,d\theta \le 2 \pi \|f\|_{\infty}.$$
But for any polynomial $f$, you can check that $I(f)=0$. Hence by continuity, $I(f)=0$ for any $f$ in the closure of the polynomials. On the other hand, for $f(z)=\bar{z}$, $I(f) = 2\pi i$, so $f(z)=\bar{z}$ is not in the closure.
(This proof is easy to discover when you know the Cauchy integral theorem, which says that any holomorphic function has $\int_{S^1} f(z)\,dz = 0$, or indeed the same replacing $S^1$ with any nice closed curve.)