If I'm not mistaken, ss is an alternative to ß. Why is sz not an alternative? The ß seems to be nothing but an antiqua-like representation of the sz-ligature in Fraktur, and so one should expect the alternative to be sz.
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But you are mistaken. Suisse-German has no ß. They always use ss. In German German, there has been a writing reform. Since then, you use ss for short vocals, and ß for long ones ("Die Straße des Hasses.") but you can't choose between them. Before the reform, it wasn't that consistent. For Austrian German I'm not informed, but they have a ß, that's sure. – user unknown Jan 25 '17 at 01:34
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1“Unfall der Rechtschreibgeschichte”. Both, ss and sz (or rather ſs and ſz or ſʒ), have been possible replacements and origins of ß. Wherever the 21st-century orthographic rules still require ß, historically sz would have been preferred, but meanwhile almost everyone and especially the Swiss had already settled on a single replacement, which almost always was ss. While doubling of letters is a feature of German graphotactics it has in common with many others, sz would be a rather unusual digraph (despite Czech), but ſz matches tz – ch/ck would suggest cs/cſ instead! – Crissov Jan 25 '17 at 01:59
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Sz does exist in the loan words Szene and Szintillation and German speakers pronounce it as a sharp s. (About unusual digraphs common in German: pf) – Janka Jan 25 '17 at 02:18
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@Janka "Szene" is pronounced /ˈstseːnə/, not /ˈseːnə/. – Uwe Jan 25 '17 at 13:02
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Which dialect? I don't know people who pronouce a ts in Szene. Seems like an overcorrection to me. – Janka Jan 25 '17 at 13:17
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@Janka Standard pronunciation (for the meanings 1, 2, 3, 6, 7 of the linked Wiktionary article). In expressions like "Szenekneipe" or "Drogenszene" (meanings 4, 5 of the linked Wiktionary article), /ˈseːnə/ seems to be common, though. – Uwe Jan 25 '17 at 14:23
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The Fraktur typeset had ſʒ, but it simply never made it into Antiqua. See
https://de.wikipedia.org/wiki/%C3%9F#Historischer_Vergleich_als_Tabelle

Janka
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