No. If the regular expression encodes an infinite language, then there is no way to decompose it that way. Without the Kleene star, regular expressions can only express finite languages.
I realize this is a rather trivial answer, and it begs the next question: what if we are promised that the language is finite? In that case, the answer is yes. Here are two ways to see that the answer is yes:
Approach #1: Since the language is regular, we can find a DFA that recognizes it -- let's choose the minimal DFA. Since the language is finite, this DFA will not have any loops in it. Now if you apply the standard algorithm for converting a DFA to a regular expression, the result is a star-free regular expression. In fact, you get out only a single regular expression.
Approach #2: If the language is finite, then you can enumerate all of the words in the language, say $L=\{w_1,w_2,\dots,w_n\}$. Therefore $w_1 + w_2 + \dots + w_n$ is a regular expression for $L$.
Credit: The answer for the case where the language is finite is due to @J.E. Pin.