Godel proved there are true statements in arithmetic that can't be proven true in any sufficiently strong Formal Axiomatic System (FAS). The authors of this paper use similar arguments to prove there are TM's that belong to a certain complexity class that cannot be proven to belong to that class. They refer to these type of algorithms as "hidden machines".
ON THE EXISTENCE OF HIDDEN MACHINES IN COMPUTATIONAL TIME HIERARCHIES
What happens to the quesion of P?NP if there exists a TM that can solve any satisfiable 3SAT instance in polynomial steps, yet, it is impossible to prove this TM does so?