Questions tagged [concentration]

The concentration characterizes the composition of a mixture with respect to the volume of the mixture. There are mass, amount, number and volume concentrations. Related and within the scope of this tag are normality, molality, mole fraction/ratio, mass fraction/ratio.

The concentration characterizes the composition of a mixture with respect to the volume of the mixture. It is a group of four quantities: mass, amount, number and volume concentration. It is also usually used as the short form for amount (of substance) concentration.

Related and within the scope of this tag are normality, molality, mole fraction/ratio, mass fraction/ratio.

Mass concentration

  • Mass of a constituent divided by the volume of the mixture.
  • Symbol: $\rho, \gamma$
  • SI Unit: $\rho_i = \frac{m_i}{V} = \mathrm{\frac{kg}{m^3}}$
  • Common units: $\mathrm{\frac{g}{L}}$

Amount concentration

  • Amount of a constituent divided by the volume of the mixture. For entities $B$ it is often denoted as $[B]$
  • Synonyms amount-of-substance concentration, substance concentration, molar concentration, molarity
  • Symbol: $c$
  • SI Unit: $\phi_i = \frac{n_i}{V} = \mathrm{\frac{mol}{m^3}}$
  • Common units: $\mathrm{\frac{mol}{L}}=\mathrm{\frac{mmol}{mL}}=\mathrm{\frac{mol}{dm^3}}$ (Often denoted as $M$)

Number concentration

  • Number of entities of a constituent in a mixture divided by the volume of the mixture.
  • Symbol: $C, n$
  • SI Unit:$\phi_i = \frac{N_i}{V} = \mathrm{m^{-3}}$

Volume concentration

  • Volume of a constituent of a mixture divided by the sum of volumes of all constituents prior to mixing.
  • Synonym: volume fraction
  • Symbol: $\phi$
  • SI Umit: (dimensionless) $\phi_i = \frac{V_i}{V} = \mathrm{1}$
  • Common Units: $\mathrm{\frac{L}{L}}$, or expressed as numbers $0.5$ or $50\%$

Related Normality

  • Entity corresponding to the transfer of a $\ce{H+}$ ion in a neutralization reaction, of an electron in a redox reaction, or to a magnitude of charge number equal to 1 in ions.
  • Examples: $\ce{\frac12 H2SO4, \frac15 KMnO4, \frac13 Fe^{3+}}$
  • Synonyms: equivalent concentration, equivalent entity
  • IUPAC discourages the use of this

Related Molality

  • Amount of entities of a solute divided by the mass of the solvent
  • Symbol: $m, b$
  • SI Unit: $b_i = \frac{n_i}{m_{\mathrm{solvent}}} = \mathrm{\frac{mol}{kg}}$

Related Mole fraction

  • Amount of a constituent divided by the total amount of all constituents in the mixture.
  • Synonym: Amount fraction
  • Symbol: $x$ ($y$ for gaseous mixtures)
  • SI Unit: (dimensionless) $x_i = \frac{n_i}{n} = \mathrm{1}$
  • Common units: $\mathrm{\frac{mol}{mol}}$. parts per million/billion/trillion (ppm/b/t)
  • Mole ratio: $r_i = \frac{n_i}{n - n_i}$

Related Number fraction

  • the number of entities of one constituent divided by the total number of entities in the mixture.
  • equal to mole fraction

Related Mass fraction

  • Mass of a constituent divided by the total mass of all constituents in the mixture.
  • Symbol: $w$
  • SI Umit: (dimensionless) $w_i = \frac{m_i}{m} = \mathrm{1}$
  • Common units: $\mathrm{\frac{kg}{kg}}$. parts per million/billion/trillion (ppm/b/t)
  • Mass ratio: $\zeta_i = \frac{m_i}{m - m_i}$

Further reading

Related Tags

760 questions
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How to calculate the concentration based on dilution of a stock solution?

One of my exam questions is about lipstick and calculating the amount of lithium in the lipstick by AAS. The determination took place by making standard solutions with known concentrations of lithium. For the stock solution $653.3~\mathrm{mg}$…
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Effect of evaporation on the concentration of a saturated solution

When evaporating a saturated solution, does the concentration remain the same? My thinking is that because the solution is saturated, and the volume is decreased, the excess solute would precipitate out of the solution. Therefore maintaining the…
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Can molarity ever exceed molality

Work so far: Molality = mol solute/kg solvent Molarity = mol solute/L solution So for molarity to exceed molality in the same solution, the numerical value of kg of solvent > L of solution From my experience this never happens. However by applying…
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How to calculate the parts-per-million concentration from a percent concentration?

I am asked to find the concentration of magnesium ions in ppm for a $0.025\ \%$ solution of $\ce{MgCl2}$. I can use this formula: $$\text{concentration in ppm} = \frac{\text{mass solute}_\mathrm{(g)}}{\text{mass…
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Should residual sodium be considered in measuring sodium content of sweat?

I read an article, "Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis", which describes the design of a wearable band that detects various components in sweat in order to monitor the wearer's health. One of the…
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How to measure ppm of copper

What is the best way to measure ppm of copper in colloidal solution. My TDS meter only shows at 2ppm which cannot be correct.
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Molar concentration calculation with absolute uncertainty

A solution of $\ce{F-}$ is prepared by dissolving $(0.0933\pm0.0004)\ \mathrm g$ of $\ce{NaF}$ $(M= (41.989\pm0.001)\ \mathrm {g/mol})$ in $156.00\pm\ \mathrm{mL}$ of water. Calculate the concentration of $\ce{F-}$ in the solution and its absolute…
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How can inconsistencies in these sodium chloride solutions be explained?

I'm entirely chemically-naive and am confounded when trying to convert $\ce{NaCl}$ brine concentrations to moles per litre. The situation is that I'm performing linear multiple regressions using published data form multiple studies. Because the…
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How to calculate molarity of a solution by solving the percentage?

Molarity is number of moles per litre of solution and we calculate it by simply dividing moles by volume. But, if moles are not given and the w/w or w/v percentage is given then, how can we solve for the molarity? For example, if we have 2 % w/v…
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How to prepare solutions of different concentrations of potassium from stock solutions with different concentartions?

I need to prepare different concentrations of $\ce{K+}$ ($10$, $20$, $30$, $40$, $\pu{50 mM}$) by diluting a solution of $\pu{100 mM}$ $\ce{K+}$ with an isotonic buffer of $\pu{5 mM}$ $\ce{K+}$. I need $\pu{4 mL}$ of each concentration. I really…
Jenny
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Can I convert from an emission amount (in tonnes per area) to a concentration (in ppbv)?

Hi, I was wondering if it is possible to estimate the concentration of SO2 given the total mass of SO2 emissions? Europa's EDGAR has a resource called "Global Emissions EDGAR v4.2" (see http://edgar.jrc.ec.europa.eu/overview.php?v=42). A database…
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Electronic oxygen concentration sensor

I bought an electronic meter which measures the concentration of oxygen in air. But I think the sensor has failed because it is too old, as it had a crusty substance coming from it.but I can no longer find spare sensors for it. How might this sensor…
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Reduction of molality of methanol

How many grams of water would you add to $\pu{1.00 kg}$ of $\pu{1.44m}$ $\ce{CH3OH (aq)}$ to reduce the molality to $\pu{1.00 m}$ $\ce{CH3OH}$? I have tried $M_1V_1=M_2V_2$. I have tried converting it to kg of $\ce{CH3OH}$ and subtracting it from…
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Concentrating Isopropyl alchohol using non-iodized salt

I am using 99% isopropyl alchohol to clean soldering flux residues for my electronics projects. Due to a certain viruse running amok in the world today, I am not able to get from my usual supplier. I am running low on supplies. So i got this idea…
Jake quin
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Shouldn't mineral NPK fertilizer ingredients add up to 100%?

I use a mineral based fertilizer in powder form which - according to the label - should not contain any fiber and is fully soluble in water (I dissolved 2 times the recommended dosage and found no solids remaining in the solution): The NPK + Mg +…
CuriousIndeed
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