In 2016 synthesis and structure of tetranitratoethane $\ce{C2H2N4O12}$ were reported [1]. Currently (as of 2017-Q4) this is the only dinitrato-carbon compound with the well-established crystal structure and composition:
This article also mentions dinitratomethane (reference number updated from 6 to 2):
While nitrate esters such as nitroglycerin (NG) and pentaerythritoltetranitrate (PETN) (Figure 2A and B) are well known, only very few examples of germinal C-nitrato compounds are known. The simplest one, dinitratomethane (Figure 2C) is a liquid which is obtained from nitration of 1,3,5-trioxane in a $\ce{HNO3/H2SO4}$ mixture [2].
Figure 2. Structural formula of nitroglycerin (A), PETN (B), and dinitratomethane (C).
However, I wasn't able neither to get the full-text of original paper from 1938, nor any more recent proofs of existence for dinitratomethane. Google Scholar returns only a couple of entries one of which is [1], and another one is a PhD thesis. There are also zero Ngrams for "dinitratomethane", which is unusual. ChemSpider also lists this compound as nitrooxymethyl nitrate (CAS 38483-28-2).
Can anyone approve or disapprove the existence of dinitratomethane $\ce{CH2N2O6}$ (feel free to utilize computational chemistry too)?
References
- Fischer, D.; Klapötke, T. M.; Stierstorfer, J. Chem. Comm. 2016, 52 (5), 916–918. DOI: 10.1039/C5CC09010E.
- G. Travagli, Gazz. Chim. Ital., 1938, 68, 718.