3

I came across a question asking me the reason for the lustrous appearance of many metals. The answer stated that it was due to the presence of free electrons in the metal. But I don't understand how this works. How do the free electrons affect the reflection of light from the metallic surface?

Thanks.

Berry Holmes
  • 4,124
  • 3
  • 23
  • 44
devb
  • 261
  • 1
  • 4
  • 8
  • Free electrons have continuous energy spectrum, so they can respond to electromagnetic radiation of any wavelength. Also, related: https://chemistry.stackexchange.com/questions/72818/is-chromium-the-shiniest-metal – Ivan Neretin Apr 21 '17 at 10:04
  • 1
    see also the answers to this question https://chemistry.stackexchange.com/questions/16633/why-is-gold-golden – porphyrin Apr 21 '17 at 10:16

1 Answers1

7

Light is an electromagnetic wave. A metal has a large cloud of relatively free electrons (electrons that are loosely bound to the metal surface). When a beam of light is incident on a metal surface, it polarizes the electron cloud, i.e. some regions on the metal become relative more "positive" while some regions relatively become more "negative". Thus, this induces a field which makes the electrons to start oscillating. This oscillation generates another electromagnetic wave which opposes the incident radiation, (An ideal metal will completely oppose the incident light radiations), and hence our incident light rays get reflected.

Berry Holmes
  • 4,124
  • 3
  • 23
  • 44