Are molecules exchanged between a solid and liquid in equlibrium?

Question

In Vapor-Liquid Equilibrium, it is my understanding that molecules exchange between the gas and liquid continuously; even when no difference in temperature or partial pressure exists.

Regarding Solid-Liquid Equilibrium; is there a similar continuous exchange of molecules? For example on a single crystal of ice submerged in pure water at perfect and constant 0°C, will molecules on the surface of this crystal exchange with the liquid? In the past I have assumed this to be the case, but now realize I have not seen a reference that explicitly details this like is common for vapor-liquid equilibrium. Are there any references that calculate the rate at which this occurs? Side question, is there also a continuous exchange for solid-gas equilibrium?

Yes, and yes. All solids have some vapor pressure, and (often negligible) solubility. — Mithoron, Jun 05 '22 at 20:48
Generally, molecules/atoms/ions have no means for awareness the system is in equilibrium, being "instructed to do nothing". Additionally, they do not have temperature. A single kinetic energy value belongs to a wide range of possible system temperatures, so they are changing a phase at will. — Poutnik, Jun 06 '22 at 08:20
Your question was already answered https://chemistry.stackexchange.com/questions/73344/proof-of-dynamic-nature-of-equilibrium — Pulkit Sharma, Jun 08 '22 at 03:55
Does this answer your question? Proof of Dynamic Nature of Equilibrium — Pulkit Sharma, Jun 08 '22 at 03:55

score 15 · Accepted Answer · answered Jun 05 '22 at 21:03

Even two solids in contact may exchange atoms, such as gold in contact with lead. Accidental cold-welding is a serious problem in space technology, in particular.

You can prove to yourself that ice/water, in equilibrium, exchanges molecules: immerse an ice-cube on a string in water at 0°C, and the cube will slowly change shape. "No chemist ever observes the same ice cube twice..." as Heraclitus or Heisenberg stated (I'm not certain).

Are molecules exchanged between a solid and liquid in equlibrium?

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