For example in the following compounds
- CoCl3.6H2O
- CoCl3.6NH3
- CoCl3.5NH3
- CoCl3.4NH3
in all of these complexes, we took the
a)oxidation state of Cobalt as +3 ( since there are 3 Cl- ions and NH3 and H2O are neutral ligands )
b) Co-ordination number of Cobalt as 6
and the answer to writing the compounds was:
1.[Co(H2O)6]Cl3 or [Co(H2O) 5Cl]Cl2.H2O
[Co(NH3)6]Cl3
[Co(NH3)5Cl]Cl2
[Co(NH3)4Cl2]Cl
My question is this: Why do we take the co-ordination number of Cobalt always six?
Can't Co take other co-ordination numbers like 4? or 5?
So for the following compound
CoCl3.4NH3
Can't we write it as [Co(NH3)4]Cl3 instead of
[Co(NH3)4Cl2]Cl
Also how to predetermine the C.N of the central metal atom just by looking at anions and ligands? (cases when no coordination sphere is marked like in my above examples)