Chemistry of Aromaticity. What's non hückel double bond ?
What are the difference between hückel and non-hückel double bond ?
[ Here, in figure the green one is non hückel double bond ]
Asked
Active
Viewed 838 times
0

Chemistry lover
- 1
- 3
-
2There is no intrinsic difference. Hückel's rule counts the number of pi electrons in a closed ring. It says nothing about other double bonds. – Karl Jul 14 '19 at 23:26
1 Answers
1
In the given molecule Pyrene , the π bond shown in green is in cross conjugation (shown in green in figure 1). This bond( figure 2) is excluded from interaction with rest of conjugated system. Hence , the central $\ce{C=C}$ isn't hosted by the largest p orbital loop, so it's not counted towards Hückel's rule for aromaticity.
The outer periphery (shown in blue in figure 3), is a loop of $\ce{14 π}$ electrons , therefore aromatic. This may be possible hückel double bond you are referring to.
The π bond in cross-conjugation (shown in green) maybe non-hückel double bond.

Chakravarthy Kalyan
- 4,354
- 1
- 15
- 33
-
4Beware: The central pi bond does not count towards the Hückel rule, however that does NOT mean that bond is not part of the aromatic system! – Karl Jul 14 '19 at 23:23