That's a good question with a non-intuitive answer. The main point is: one has to distinguish stellar systems from stars themselves. Consider an essemble of 30 stellar systems. 33% or 10 of them are double stars. Then we have overall 40 stars where 20 of them (50%) are stars in multiple systems.
The reality here is complicated. There is a review article by Gaspard Duchêne and Adam Kraus on stellar multiplicity. They provide a table of the frequency of multiplicity:
- $< 0.1$ solar masses: 22%
- $0.1 - 0.5$ solar masses: 26%
- $0.7 - 1.3$ solar masses: 44%
- $1.5 - 5$ solar masses: >50%
- $8 - 16$ solar masses: >60%
- $>16$ solar masses: > 80%
These probabilities have to be folded with the initial mass function to see how much these probablities impact the overall number. While I didn't find a paper which does this exactly, looking at the IMF diagramme, and the fact, that multiplicity is already above the threshold of 33% for masses > ~0.5 solar masses, the majority of stars will be in multiple systems while most systems are single star systems. This argument also so far did not consider multiplicity higher than two - which further helps this argument.
However, there is the RECONS census from 2018 of the solar neighbourhood within the nearest 10 parsec. This sample consists of 317 systems, which of 232 are found to be single and overall 378 stars and 50 brown dwarfs are found. The numbers from this survey give us that there are 232/(378+50) = 54% single stars (or brown dwarfs). There is an update regarding this sample using the Gaia data from 2021 by Reyle et al which conclude
Almost half of the stars and brown dwarfs are in multiple systems. As summarised in the bottom part of Table 3, our 10 pc sample contains 246 single, 69 double, 19 triple, three quadruple, and two quintuple systems
Thus the thorough sample, and assuming that our solar neighbourhood is representative, gives us the idea that it might possibly be so that both, most stars systems are single systems and that about half of the stars are single stars. Surveys for a slightly larger range (but less rigorous) point into the same direction.
Thus it might actually be that the initial assumption of half the stars in the Galaxy being binaries does not quite hold. Instead likely both, most stars and most stellar systems, might be single.