Let $G\subseteq GL_n(\mathbb R)$ and let $\mathfrak g$ denote its Lie algebra.
Let $e: \mathfrak g \to G$ be the map $X \mapsto e^X$.
Does there exist an example of $G$ and $\mathfrak g$ such that $e$ is not injective?
Of course I think the answer is no, there is no such example because $e: \mathbb R \to \mathbb R$ is injective.
What about $G\subseteq GL_n(\mathbb C)$?
Since the map is the same I again think there should not exist such an example.