I will use definitions and methods from P. Freitas' paper here. Sometimes I will refer to the paper as $[\text{F}]$.
$K$ and $J$ functions. First of all we define $K$ and $J$ functions as the following.
$$\begin{align}
K(r,p,q):=& \int_0^1\frac{\ln^r(x)\operatorname{Li}_p(x)\operatorname{Li}_q(x)}{x}\,dx, \\
J(m,p,q):=& \int_0^1 x^m\operatorname{Li}_p(x)\operatorname{Li}_q(x)\,dx.
\end{align}$$
Note that $K(r,p,q)=K(r,q,p)$ and $J(m,p,q)=J(m,q,p)$. Furthermore $K(0,p,q)=J(-1,p,q)$ and we could reduce it to rational constans and zeta values at positive integers as we will show it in Result $2$. There is a much more general result about $J$ in $[\text{F}]$ Theorem $1$, that we also could simplify it to rational constants and zeta values at positive integers for any $(m,p,q) \in \mathbb{Z}^3$, with $p,q\geq 1$ and $m \geq -2$.
As you have shown your problem is equivalent to find $K(1,2,2).$
$S_{p,q}$ function. Let $S_{p,q}$ be the family of the following linear sums
$$S_{p,q} := \sum_{n=1}^{\infty} \frac{H_n^{(p)}}{n^q},$$
where $H_n^{(p)}:=\sum_{j=1}^n j^{-p}$ finite sums are the generalized harmonic numbers.
We will use some results from Freitas' paper.
Result $1$. For the $K$ function it is true, that
$$K(r,p,q)=-rK(r-1,p,q+1)-K(r,p-1,q+1).$$
For the proof see $[\text{F}]$ Lemma $3.7$ at page $9$, and the proof of Theorems $1$ and $2$ also at page $9$. By applying this repeatedly we see that we are able to reduce the original integral to integrals of the form $K(0,p',q')=J(-1,p',q')$ and integrals $K(i,0,p+q+r-i)$ with $i=1,\dots,r$.
Result $2$. For $p,q \geq 1$ the integral $J(-1,p,q)$ is reducible to zeta values. If $p \geq q$, we have
$$J(-1,p,q) = (-1)^{q+1}\left(1+\frac{p+q}{2}\right)\zeta(p+q+1)+2(-1)^q\sum_{j=1}^{\lfloor q/2\rfloor} \zeta(2j)\zeta(p+q-2j+1)+\frac{(-1)^q}{2}\sum_{j=1}^{p-q} \zeta(j+q)\zeta(p-j+1).$$
Since $J(-1,p,q)=J(-1,q,p)$ there is a similar expression for $p<q$. More details at $[\text{F}]$ Theorem $3.3$ at page $6\!-\!7$. You will also find the proof of the statement there.
Result $3$. We also want to simplify $K(r,0,q)$, which expression appers while using Result $1$. For the case when $w=r+q$ weight is even, there is a nice expression at $[\text{F}]$ Theorem $3.1$ at page $5$, with we can simplify $K(r,0,q)$. Sadly according to $[\text{F}]$ there is not a general expression in case when $w=r+q$ is odd. While evaluating your integral we will run into this odd case. But luckily we are not completly lost! As $[\text{F}]$ Lemma $2.1$ at page $4$ says, there is a connection between $S_{r,q}$ and $K(r-1,0,q)$. This is the following. For $q,r \geq 2$ we have
$$S_{r,q}=\zeta(r)\zeta(q)-\frac{(-1)^{r-1}}{(r-1)!} \int_0^1 \frac{\ln^{r-1}(x)\operatorname{Li}_q(x)}{1-x}\,dx=\zeta(r)\zeta(q)-\frac{(-1)^{r-1}}{(r-1)!}K(r-1,0,q),$$
or express it to $K(r-1,0,q)$ we get
$$K(r-1,0,q)=(-1)^{1-r}(r-1)!\left(\zeta(r)\zeta(q)-S_{r,q}\right).$$
You also find the proof at page $4$.
Evaluating your integral. First we will use Result $1$ twice. First time for $K(1,2,2)$ and second time $K(1,1,3)$. Thus
$$K(1,2,2)=-K(0,2,3)-K(1,1,3)=-\color{red}{K(0,2,3)}+\color{green}{K(0,1,4)}+\color{blue}{K(1,0,4)}.$$
Evaluating $\color{red}{K(0,2,3)}$ and $\color{green}{K(0,1,4)}$. From the definition of $K$ and $J$ we know that $K(0,2,3)=J(-1,2,3)$ and $K(0,1,4)=J(-1,1,4)$. Now we can use Result $2$. I know that you don't like using CAS, but because Result $2$ contains only elementary operations, such as finite sums, I let this calculation to Maple. I've defined the following function.
Je:=(p,q)->(-1)^(q+1)*(1+(p+q)/2)*Zeta(p+q+1)+2*(-1)^q*sum(Zeta(2*j)*Zeta(p+q-2*j+1),j=1..floor(q/2))+((-1)^q/2)*sum(Zeta(j+q)*Zeta(p-j+1),j=1..p-q);
Je(2,3)
and Je(1,4)
will do the job. Using Maple or calcaulate it by hand we get
$$\begin{align}
J(-1,2,3)=&\frac{1}{2}\zeta^2(3), \\
J(-1,1,4)=&\frac{7}{4}\zeta(6)-\frac{1}{2}\zeta^2(3) = \frac{1}{540}\pi^6 - \frac{1}{2} \zeta^2(3).
\end{align}$$
Evaluating $\color{blue}{K(1,0,4)}$. Because $1+4=5$ is odd we could use just the connection to $S_{2,4}$. By Result $3$ we get
$$K(1,0,4)=S_{2,4}-\zeta(2)\zeta(4).$$
This paper by P. Flajolet and B. Salvy $[\text{FS}]$ states that
$$S_{2,4}=\sum_{n=1}^{\infty} \frac{H_n^{(2)}}{n^4} = \zeta^2(3)-\frac{1}{3}\zeta(6)=\zeta^2(3)-\frac{1}{2835}\pi^6.$$
Details about linear sums are also in $[\text{FS}]$. In $[\text{FS}]$ Theorem $3.1$ at page $22$ states that there is an expression to evaluate $S_{p,q}$ when $m=p+q$ weight is odd. This is an analogous situation what we have seen in Result $3$. Fortunately $[\text{FS}]$ page $22\!-\!23$ talks about the even case, which is our case for now, because $2+4=6$ is even. Using this we get
$$K(1,0,4)=\zeta^2(3)-\frac{1}{3}\zeta(6)-\zeta(2)\zeta(4)=\zeta^2(3)-\frac{25}{12}\zeta(6)=\zeta^2(3)-\frac{5}{2268}\pi^6.$$
Putting this all together.
$$K(1,2,2)=-\color{red}{K(0,2,3)}+\color{green}{K(0,1,4)}+\color{blue}{K(1,0,4)}=-\color{red}{\frac{1}{2}\zeta^2(3)}+\color{green}{\frac{7}{4}\zeta(6)-\frac{1}{2}\zeta^2(3)}+\color{blue}{\zeta^2(3)-\frac{25}{12}\zeta(6)}=-\frac{\zeta(6)}{3}=-\frac{\pi^6}{2835},$$
and this completes the proof.