This leads to the same answer as @user2345215's response, but hopefully motivates it more.
In Pokemon (at least in Pokemon Go) you have regular balls with which to catch pokemon, as well as "enhanced" balls which have a higher chance to catch a given pokemon, called great balls. I may not have the details exactly right, but the way they handle this "higher chance" is nice, and could impart meaning to "twice as likely".
Suppose the chance to catch charizard with a regular ball is 10%.
We want the chance of catching it with a great ball to be "doubled" in some sense that still holds were we to apply this discussion to pikachu, whose chances are 60%.
What Pokemon does is to give great balls a $2 \times$ "multiplier": the chance of catching charizard with a great ball equals the chance of catching it given two regular balls, which equals the chance of catching it on the first throw + the chance of catching it on the second:
$$
p_{great} = p_{reg} + (1-p_{reg})*p_{reg}
$$
Thankfully this never exceeds 1 (which can be checked) and gives a nice meaning to twice as likely. In the example above, a great ball has a 19% chance of catching a charizard. In fact, "twice as likely" only ever equals $2p_{reg}$ when the probability is zero; otherwise it's always strictly less than 2.
I'm trying to think of real life examples where "twice" or "$5$ times" as might be used.
These facts tend to be quoted for things with already very low chances, like smokers dying of lung cancer, in which case the author simply means $2p$, or $5p$. So let me invent an example, which MIGHT be true, where the distinction matters:
A randomly chosen male is twice as likely to have experienced a car accident as a female.
70% of females have experienced a car accident.
Here the "pokemon" are car accidents and pokeballs are sequential draws of males or females, respectively.
The chance of seeing accident history by drawing one random male, equals the chance of seeing accident history with two randomly drawn female lifetimes; 91%.