You cannot prove that the two-variable limit equals the iterated limits even if they both exist, since the two-variable limit may fail to exist even if both iterated limits exists and are equal. For example, take $f(x,y) = \frac{xy}{x^2+y^2}$, with $a=b=0$. The iterated limits both exist:
$$\lim_{x\to 0}\left(\lim_{y\to 0}\frac{xy}{x^2+y^2}\right) = \lim_{x\to 0}\frac{0}{x^2} = 0,$$
$$\lim_{y\to 0}\left(\lim_{x\to 0}\frac{xy}{x^2+y^2}\right) = \lim_{y\to 0}\frac{0}{y^2} = 0.$$
But the limit does not exist as $(x,y)\to(0,0)$. If you approach $(0,0)$ along the line $y=x$ you get the limit as $x\to 0$ of $\frac{x^2}{2x^2}$, which goes to $\frac{1}{2}$, not $0$. So the two-variable limit does not exist, even though the two iterated limits both exist and are equal.
If you assume that the two-sided limit exists and is equal to $L$, and then you want to prove that the iterated limits will therefore both exist and be equal, then you might have a better shot. Start by thinking about the definitions.
Added later: And then look at Robin Chapman's example to see that it does not quite work out. So you don't get implications either way.