Let $(X, \Sigma, \mu)$ be a $\sigma$-finite measure space and $(E, |\cdot|)$ a Banach space. Here we use Bochner integral. The space $L_p := L_{p}(X, \mu, E)$ consists of (equivalence classes of) all Bochner measurable functions $f$ with values in $E$ whose norm $|f|$ lies in the standard $L_{p}(X, \mu, \mathbb R_{\ge 0})$ space.
A standard result is that if $E = \mathbb R$ and $p \in (1, \infty)$ then the continuous dual space $(L_p)^*$ of $L_p$ is indeed $L_{p'}$ where $\frac{1}{p} + \frac{1}{p'} = 1$. One of the proof relies on the continuous linear operator $T:L_{p'} \to (L_p)^*$ defined by $$ \langle T u, f\rangle := \int_X u(x)f(x)\mathrm d \mu(x) \quad \forall u \in L_{p'}, \forall f \in L_{p}. $$
Then $T$ is indeed a linear surjective isometry. However, I could not see how to use the same approach for a general Banach space $E$.
Is there such a linear surjective isometry $T$ in case $E$ is a general Banach space?