Actually all the quaternions are zeros of quadratic polynomials with real coefficients. If $q=a+ib+jc+kd$, with $a,b,c,d$ real, then
$$
(x-q)(x-\overline{q})=x^2-2ax+(a^2+b^2+c^2+d^2)
$$
has $q$ as a zero, and also has real coefficients. Here $\overline{q}=a-ib-jc-kd$ is the 'conjugate' quaternion.
In a sense the quaternions are just a bunch of copies of $\mathbf{C}$ pointing in different directions. All the copies share the real axis, but we can freely rotate the `imaginary' axis in the 3D-space spanned by $\{i,j,k\}$. Whenever $b^2+c^2+d^2=1$ the quaternion $u=ib+jc+kd$ satisfies the equation
$$
u^2=-1.
$$
Thus $u$ can take the role of the complex number $i$ in the sense that the mapping $x+iy\mapsto x+uy$, ($x,y\in\mathbf{R}$) is a monomorphism of rings from the complex number into the quaternions, so its image is a copy of $\mathbf{C}$.
(Yes, there is more to quaternions than `just a bunch of copies of $\mathbf{C}$', but for the purposes of them being zeros of polynomials with real coefficients this point of view is enough.)