The others answers give simple semantic proofs showing that LEM is independent of intuitionistic logic.
However, you don't always need to construct a model to show non-derivability. There are simple, clear proof-theoretic arguments showing the same thing, which have the advantage that they work for intuitionistic first-order predicate logic as well, without any additional work or need for modification.
One of them relies on the following important property satisfied by the intuitionistic calculus.
Disjunction property: For any formulae $M,N$, if there is an intuitionistic derivation of $\vdash M \vee N$, then we can find a derivation of either $\vdash M$ or $\vdash N$.
By the disjunction property, if $\vdash A \vee \neg A$ was provable, then we would be able to prove either $\vdash A$ or $\vdash \neg A$. But it's clear that neither of these have (even classical) derivations. Hence, $\vdash A \vee \neg A$ is not provable.
Okay, that's quick and simple, but how do we prove the disjunction property? Well, intuitionistic logic is usually defined by means of either a sequent calculus deduction system, a natural deduction system, or a Hilbert system. For the sequent calculus, we can prove it simply by looking at cut-free derivations (see [1] for a more general version). For natural deduction, we can either reduce it to the sequent calculus, or prove it directly by proof normalization (see [2]). The Hilbert system is also reducible to the sequent calculus. So I'll give the short sequent calculus version:
Recall that the sequent calculus has the following two rules for introducing $\vee$ on the right of the turnstile $\vdash$:
$$\frac{\Gamma \vdash A}{\Gamma \vdash A \vee B}\vee\!R_1$$
$$\frac{\Gamma \vdash B}{\Gamma \vdash A \vee B}\vee\!R_2$$
If $\vdash M \vee N$ has a derivation, then by the cut-elimination theorem it has a derivation that doesn't use the cut rule. Look at the last rule of a cut-free derivation of $\vdash M \vee N$. It cannot be cut, so it can only be $\vee\!R_1$ or $\vee\!R_2$. If it's $\vee\!R_1$, then the previous line was $\vdash M$, so $\vdash M$ has a derivation as claimed. Otherwise, the last rule is $\vee\!R_2$ and the previous line was $\vdash N$, so $\vdash N$ has a derivation. This proves the disjunction property.
edit: As commenters pointed out, it's worth mentioning that the negation of LEM, $\vdash \neg (A \vee \neg A)$, cannot be derived in intuitionistic logic either. To show this, all you have to do is notice that $\neg (A \vee \neg A) \vdash A$ is provable in intuitionistic logic. So if $\vdash \neg (A \vee \neg A)$ was provable as well, you'd be able to use the cut rule to conclude that $\vdash A $ would also be provable. But as we observed above, during the proof of the disjunction property, $\vdash A$ is not derivable. Thus, $\vdash \neg (A \vee \neg A)$ is not derivable either.
[1] A. S. Troelstra, H. Schwichtenberg: Basic Proof Theory, 2nd edition, 2000. ISBN 9781139168717
[2] D. Prawitz: Natural Deduction: A Proof-Theoretical Study, Dover Publications, 1965. ISBN 9780486446554x