Here's a detailed answer based on the comments above.
Suppose $c\geq 1$. Then $\sigma(c-1)=\sigma(c)-1\subseteq [0,\infty)$, so $\sigma(c)\subseteq [1,\infty)$ and hence $c$ is invertible. Notice that $\sigma(c^{-1})\subseteq (0,1]$. Thus $\sigma(c^{-1}-1)= \sigma(c^{-1})-1\subseteq (-1,0]$. So $\sigma(1-c^{-1})\subseteq [0,1)$ and hence $1-c^{-1}$ is positive, i.e., $1\geq c^{-1}$.
Notice that if $0\leq a\leq b$, then $ c^{*}ac\leq c^*bc$. Indeed, $b-a\geq 0$ implies that $b-a=d^*d$ for some $d\in\mathscr A$. Now the result follows immediately.
Next, suppose that $0\leq a\leq b$ and $a$ is invertible. Let $a^{1/2}$ denote the positive square root of $a$. Since $a$ is invertible, $a^{1/2}$ is invertible(hint: $a^{1/2}$ is the limit of a sequence of polynomials in $a$, so commutes with the inverse of $a$). Now $0\leq a\leq b$ implies that $$1=a^{-1/2}aa^{-1/2} \leq a^{-1/2}ba^{-1/2}=c\;\;\text{(because $a^{-1/2}$ is self-adjoint).}$$ Then $c$ is invertible and $1\geq c^{-1}$. So there exists $d\in\mathscr A$ such that $cd=dc=1$. Now it is easy to see that $a^{-1/2}da^{-1/2}$ is the inverse of $b$. Thus $b$ is invertible and $1\geq a^{1/2}b^{-1}a^{1/2}$. Furthermore, an application of the above lemma gives $a^{-1}\geq b^{-1}\geq0$.