Here is a systematic way to find counterexamples. Note that $\mathbb{F}_{2^n}$ has a primitive $m$th root of unity iff $m\mid 2^n-1$, since its multiplicative group is cyclic of order $2^n-1$. This means that if you take a primitive $m$th root of unity, the field extension of $\mathbb{F}_2$ that it generates will have $2^n$ elements for the least $n$ such that $m\mid 2^n-1$. (Note that if $m$ is odd then such an $n$ always exists, since $2$ is invertible mod $m$ and so some power of $2$ is $1$ mod $m$.)
In particular, if $m$ is odd and not one less than a power of $2$, then a primitive $m$th root of unity will be a primitive element of $\mathbb{F}_{2^n}$ for this value of $n$ but will not have order $2^n-1$. Lord Shark the Unknown's example takes $m=5$, the smallest odd number that is not one less than a power of $2$, for which $n=4$.