I know there are no integers for which the value is specifically a perfect square for the first 73 integers because I plugged the function $\sqrt{\lfloor{e^{\lfloor{x}\rfloor}}\rfloor}-\lfloor{\sqrt{\lfloor{e^{\lfloor{x}\rfloor}\rfloor}}}\rfloor$ into Desmos. There are no zeroes up to that point, and this expression would be zero (as the two terms would be the same) if this satisfied the condition.
Desmos has trouble calculating this above 73, so I couldn't check higher than that. I wonder if there is any way to prove that any such integers exist, or whether they are unlikely/likely to exist. I guess that as n gets higher, perfect powers and values of e^n get more spaced out, so it gets less and less likely for them to land on the same integer, however I do not know how to find the probability of this or prove it.