Eratosthenes could have used his friend Archimedes's work on the quadrature of parabolic segments to obtain upper and lower bounds on the value of $\alpha - \tfrac{\pi}{2}$, or indeed any acute angle $\eta$, given its sine:
$$
\frac{8\sin\tfrac{1}{2}\eta - \sin\eta}{3} < \eta <
\frac{4\tan\tfrac{1}{2}\eta + \sin\eta}{3}
\quad \left(0 < \eta \leqslant \frac{\pi}{2}\right).
$$
A modern proof is short, so we get it out of the way first. The result has the form $f(\eta) < 3\eta < g(\eta)$, where $f(0) = g(0) = 0$, so it is enough to prove $f'(\eta) < 3 < g'(\eta)$, for all $\eta$ such that $0 < \eta < \tfrac{\pi}{2}$.
Taking the upper bound first, and writing $\cos\eta = y$, we have $0 \leqslant y < 1$, and:
$$
g'(\eta) - 3 = \cos\eta + 2\sec^2\tfrac{1}{2}\eta - 3 =
y + \frac{4}{1 + y} - 3 = \frac{1 - 2y + y^2}{1 + y} = \frac{(1 - y)^2}{1 + y} > 0.
$$
As for the lower bound:
$$
3 - f'(\eta) = 3 - 4\cos\tfrac{1}{2}\eta + \cos\eta =
3 - 4\cos\tfrac{1}{2}\eta + 2\cos^2\tfrac{1}{2}\eta - 1 =
2\left(1 - \cos\tfrac{1}{2}\eta\right)^2 > 0,
$$
and as this is true for all $\eta \ne 4n\pi$, we even have $f(\eta) < 3\eta$ for all $\eta > 0$, needing no upper bound. $\square$
Recalling the trigonometric identities
\begin{align*}
\tan\left(\tfrac{1}{2}\sin^{-1}x\right) & = \left(1 - \sqrt{1 - x^2}\right)/x
&& (|x| \leqslant 1, \ x \ne 0), \\
\sin\left(\tfrac{1}{2}\sin^{-1}x\right) & =
\tfrac{1}{2}\left(\sqrt{1 + x} - \sqrt{1 - x}\right)
&& (|x| \leqslant 1),
\end{align*}
we can rewrite the theorem just proved as:
$$
\frac{4\left(\sqrt{1 + x} - \sqrt{1 - x}\right) - x}{3} < \sin^{-1}x <
\frac{4\left(1 - \sqrt{1 - x^2}\right) + x^2}{3x} \quad (0 < x \leqslant 1).
$$
In the case of present interest:
$$
\frac{8\sqrt{5} - 8\sqrt{3} - 1}{12}
< \sin^{-1}\left(\frac{1}{4}\right) <
\frac{64 - 16\sqrt{15} + 1}{12}.
$$
In radians, this is $0.2526781133 < \eta < 0.2526888717$, or $\eta = 0.2526835 \pm .0000054$.
Converting to degrees, and adding $90^\circ$, we get $104.477383947^\circ < \alpha < 104.47800588^\circ$, or:
$$\alpha = 104.47770^\circ \pm 0.00031^\circ.$$
Converting to degrees, minutes and seconds of arc, we get $104^\circ28'38.6'' < \alpha < 104^\circ28'40.8''$, or:
$$\alpha = 104^\circ28'39.7'' \pm 0^\circ00'01.1''.$$
The conversion factor $180/\pi$ needed here is obtained by long division by an estimate of $\pi$, which can be obtained by exactly the same method. Rather than perform the laborious computation needed to obtain once and for all a sufficiently accurate value of $\pi$, we shall just do enough to give a general idea.
Even the crudest estimate using the theorem, given by substitution in the equation $\pi = 2\sin^{-1}1$, isn't bad: $(8\sqrt{2} - 2)/3 < \pi < 10/3$, or $\pi = 3.22 \pm 0.11$, but we do significantly better than this by substituting in $\pi = 6\sin^{-1}\tfrac{1}{2}$, using the half-angle identities recalled above, as well as this one:
\begin{gather*}
\cos\left(\tfrac{1}{2}\sin^{-1}x\right) =
\tfrac{1}{2}\left(\sqrt{1 + x} + \sqrt{1 - x}\right)
\quad (|x| \leqslant 1). \\
\tan\frac{\pi}{12} = 2 - \sqrt{3}, \quad
\sin\frac{\pi}{12} = \frac{\sqrt{6} - \sqrt{2}}{4}, \quad
\cos\frac{\pi}{12} = \frac{\sqrt{6} + \sqrt{2}}{4}, \\
4\sqrt{6} - 4\sqrt{2} - 1 < \pi < 17 - 8\sqrt{3}, \\
\text{i.e. } 3.141104722 < \pi < 3.143593539, \\
\pi = 3.1423 \pm 0.0012.
\end{gather*}
Explicit algebraic Euclidean-constructible bounds remain tractable for hand computation even when we apply the half-angle formulae again, substituting in $\pi = 12\sin^{-1}\tfrac{\sqrt{6} - \sqrt{2}}{4}$:
\begin{gather*}
\tan\frac{\pi}{24} =
\frac{1 - \cos\frac{\pi}{12}}{\sin\frac{\pi}{12}} =
\frac{4\cos\frac{\pi}{12} - 2\cos\frac{\pi}{6} - 2}
{2\sin\frac{\pi}{6}} = \sqrt{6} + \sqrt{2} - \sqrt{3} - 2, \\
\sin\frac{\pi}{24} =
\frac{\tan\frac{\pi}{24}}{\sqrt{1 + \tan^2\frac{\pi}{24}}}, \\
\frac{\sqrt{6} + \sqrt{2} - \sqrt{3} - 2}
{\sqrt{\sqrt{16} + 8\sqrt{3} - 10\sqrt{2} - 6\sqrt{6}}}
- \sqrt{6} + \sqrt{4}
< \pi <
17\sqrt{6} + 15\sqrt{2} - 16\sqrt{3} - 32, \\
\text{i.e. } 3.141561971 < \pi < 3.141716142, \\
\pi = 3.141639 \pm 0.000077.
\end{gather*}
This is the estimate of $\pi$ obtained by inscribing a regular
icositetragon in a circle, and erecting major and minor parabolic
segments on each of its $24$ sides. It considerably improves the
estimate made by Archimedes using inscribed and circumscribed
regular enneacontahexagons ($96$-sided polygons), while involving
less computation; but it is still not as good as the
approximation $\pi \bumpeq \tfrac{355}{113}$.
In this accelerated variant of Archimedes's construction (and also of Viète's formula, except that if we follow Archimedes we start with a hexagon instead of a square - although a square is also acceptable), we start with a regular $m$-gon inscribed in the unit circle in $\mathbb{C}$,
with one vertex being $1$, and the next in anticlockwise order being
$z_0 = x_0 + iy_0$, where the value of $x_0 = \cos(2\pi/m)$ is supposed to be already known. We have chosen $m = 6$, so $x_0 = \cos(\pi/3) = 1/2$. For $n \geqslant 0$, recursively create a $2^nm$-gon, by bisecting the arcs between the
vertices of the preceding $2^{n-1}m$-gon when $n \ne 0$.
The usual method of computation, associated with Viète's formula,
which is indeed well suited to the use of a calculator (see e.g.
here), uses the recursive formula $2x_{n+1}=\sqrt{2 + 2x_n}$, and
the area of the inscribed polygon, $A_n = 2^{n-1}my_n$. This is of
course a strict lower bound for $\pi$. One can also get a strict
upper bound for $\pi$ from the area of the circumscribed polygon,
which is $A_n/x_n^2 = A_{n+1}/x_{n+1}$. What I noticed when working
on the other question was that an arithmetic mean of these
two areas,
$$
\frac{A_n + 2A_n/x_n^2}{3} =
\frac{A_n}{3}\left(1 + \frac{4}{1 + x_n}\right),
$$
gives a much better approximation to $\pi$ than either $A_n$ or
$A_n/x_n^2$ separately, and it always seems to be an overestimate.
I had already thought of using parabolic arcs for the present
question (but had no idea how it would work out in detail), and I
began to suspect a serendipitous connection between the two
questions!
Because the upper bound given by the theorem is much easier to work with than the lower bound (although it is not quite as precise), my suggested method for
computing $\pi$ is to follow the method for Viète's formula as
usual, but instead of using $A_n$ as the estimate for $\pi$, use the formula
highlighted above, which as we shall see is the same as the upper bound obtained
from the theorem.
It took me embarrassingly long to see how simple it is to incorporate Archimedes's own statement of his quadrature result, completely unmodified,
into the computational procedure for estimating $\pi$ (or, more generally, for estimating the area of a circular sector), thus computing the lower bound, as
well as the upper one. See Addendum 1 for an example.
Although the square roots occurring in the formulae are tractable for hand computation by any of the usual methods, one might consider evaluating them using the binomial series:
\begin{gather*}
1 - \sqrt{1 - x} = \tfrac{1}{2}\sum_{k=0}^\infty a_kx^{k+1} \quad (|x| < 1), \qquad
a_k = \frac{1\cdot3\cdots(2k-1)}{4\cdot6\cdots(2k+2)}, \\
a_0 = 1, \
a_1 = \tfrac{1}{4}, \
a_2 = \tfrac{1}{8}, \
a_3 = \tfrac{5}{64}, \
a_4 = \tfrac{7}{128}, \
a_5 = \tfrac{21}{512}, \
a_6 = \tfrac{33}{1024}, \
a_7 = \tfrac{429}{16384}.
\end{gather*}
Because $a_{k+1} < a_k$, we can estimate the remainder using the
geometric series:
$$
0 < 1 - \sqrt{1 - x} - \tfrac{1}{2}\sum_{k=0}^{p-1} a_kx^{k+1} <
\frac{a_px^{p+1}}{2(1 - x)} \quad (p \geqslant 0, |x| < 1).
$$
I don't know if this suggestion is very practical in general, but in the case of a rational sine with a small denominator, such as our $\eta = \sin^{-1}\tfrac{1}{4}$, it can yield estimates very well suited to hand calculation, such as this one (I'll skip the details of its derivation):
\begin{align*}
\eta & > \frac{1}{2^2} + \frac{1}{3\cdot2^7} +
\frac{1}{3\cdot2^{13}} + \frac{1}{3\cdot2^{14}} +
\frac{1}{3\cdot2^{15}}, \\
\eta & < \frac{1}{2^2} + \frac{1}{3\cdot2^7} +
\frac{1}{3\cdot2^{13}} + \frac{1}{3\cdot2^{14}} +
\frac{1}{3\cdot2^{15}} + \frac{1}{3^2\cdot2^{13}}.
\end{align*}
All that is then required, apart from the "seed" value of $180/\pi$, is a series of divisions by $2$, a couple of divisions by $3$, and a few additions. One could begin by tabulating the terms to be added, thus:
$$
\begin{array}{|c||c|c|c|}
\hline
& \text{radians} & \text{degrees} &
\text{deg}^{\circ}\text{min}'\text{sec}'' \\
\hline
\hline
1 & 1.00000000 & 57.29577951 & 57^\circ17'44.8062'' \\
2^{-1} & 0.50000000 & 28.64788976 & 28^\circ38'52.4031'' \\
2^{-2} & 0.25000000 & 14.32394488 & 14^\circ19'26.2016'' \\
2^{-3} & 0.12500000 & \text{etc.} & \text{etc.} \\
\hline
\end{array}
$$
Such dubious practicalities aside, it is interesting to use the binomial series to compare the upper and lower bounds from the theorem with the Maclaurin series for $\sin^{-1}x$:
$$
x + \sum_{j=1}^\infty \frac{4a_{2j}x^{2j+1}}{3} <
x + \sum_{j=1}^\infty \frac{(j+1)a_jx^{2j+1}}{2j+1} <
x + \sum_{j=1}^\infty \frac{2a_jx^{2j+1}}{3}.
$$
Comparing the three coefficients of $x^{2j+1}$:
$$
\begin{array}{|c||c|c|c|}
\hline
j & < \sin^{-1}x & \sin^{-1}x & > \sin^{-1}x \\
\hline
\hline
0 & 1 & 1 & 1 \\
% j > 0 & 4a_{2j}/3 & a_j(k+1)/(2k+1) & 2a_j/3 \\
1 & 1/6 & 1/6 & 1/6 \\
2 & 7/96 & 3/40 & 1/12 \\
3 & 11/256 & 5/112 & 5/96 \\
\hline
\end{array}
$$
There is a puzzle here. While it is immediately obvious by inspecting the coefficients that the series on the right exceeds $\sin^{-1}x$, the same is not at all true of the series on the left. (This is another instance of the sharper lower bound also being harder to work with.) We require the inequality:
$$
\frac{2a_{2j}}{a_j} \leqslant \frac{3j+3}{4j+2}
\quad (j \geqslant 1),
$$
with equality only for $j = 1$.
One way to prove this is to use the inequality between arithmetic and harmonic means, in conjunction with the Weierstrass product inequality. Thus, for $j > 1$:
\begin{gather*}
\frac{2a_{2j}}{a_j} = \frac{(2j+3)\cdots(4j-1)}{(2j+4)\cdots(4j)}
= \left(1 - \frac{1}{2j+4}\right)\cdots\left(1 - \frac{1}{4j}\right)
< \frac{1}{1 + \frac{j-1}{3j+2}} = \frac{3j+2}{4j+1},
\end{gather*}
which is slightly better than was required. $\square$
We end by giving a proof that Archimedes or Eratosthenes could have given (see Addendum 2):

We wish to obtain upper and lower bounds for the area $\theta$ of the sector $OPRQ$ of a circle, centre $O$, whose radius is taken as the unit of length. The angle at the vertex of the sector is $\eta = 2\theta$, and we are given the length of the straight line segment $QV = \sin\eta$.
It is shown below (simply, using modern methods) that: (i) there exists a unique parabola passing through $P$ and $Q$ and touching the circle at the midpoint $R$ of the circular arc $PRQ$, and the parabolic arc $PRQ$ lies inside the circular segment $PRQ$ except for the three points mentioned; and (ii) there exists a unique parabola touching the circle at $P$ and $Q$, and it lies outside the circle except at these two points. It is a well-known theorem (but it is also proved below) that if the tangents meet the axis $OR$ at the point $Z$, then the vertex of the parabola is the midpoint of $SZ$.
By Archimedes's famous quadrature result, the area of the minor
parabolic segment (as I shall call it, while I call the other the "major"
parabolic segment) is $\tfrac{4}{3}$ the area of the triangle
$\triangle QPR$, which is also $\tfrac{4}{3}$ the area of the
rectangle $QSRX$ (or equivalently, $RSPY$).
The area of the major parabolic segment is
$\tfrac{2}{3}$ of the area of the trapezium $PTUQ$
(this was clear from trigonometry, but see also Addendum 2 for a more
natural proof by synthetic Euclidean methods), just as the area
of the minor parabolic segment is $\tfrac{2}{3}$ of the area of the
rectangle $PYXQ$. Therefore, the difference between the two bounds
is given by $\tfrac{2}{3}$ of the combined area of the two little
triangles $\triangle QXU$, $\triangle TYP$.
When there is time, I will edit the diagram to show the point $Z$, lying on the other side of $R$ from $S$, and the two tangents $PZ$ and $QZ$, both of them being common to the circle and the "major" parabola.
(The diagram has now been edited suitably.)
Meanwhile, I hope it is easy to "see" that because $PZ$ and $QZ$ touch the circle, the angles $\angle OPZ$ and $\angle OQZ$ are right angles, and therefore $OZ = \sec\theta$. Given that (as is proved below) the vertex of the major parabola lies midway between $S$ and $Z$, and of course $OS = \cos\theta$, it follows that the "height" (horizontal in the diagram!) of the triangle that is inscribed in the major parabolic sector and that shares its base $PQ$ and its vertex (which has to remain nameless, because it is far too close to $R$ to be shown in the diagram!), is $\tfrac{1}{2}(\sec\theta - \cos\theta)$. Therefore, because $PQ = 2\sin\theta$, the area of the major inscribed triangle is $\tfrac{1}{2}\sin\theta(\sec\theta - \cos\theta) = \tfrac{1}{2}\tan\theta - \tfrac{1}{4}\sin2\theta$. Therefore, by Archimedes's theorem on the quadrature of a parabolic segment (we only need the simplest case, in which the base of the segment is perpendicular to the axis), the area of the major parabolic segment is $\tfrac{2}{3}\tan\theta - \tfrac{1}{3}\sin2\theta$. Therefore, the area of the circular segment $PRQ$, which (as is shown below) is contained within the major parabolic segment $PRQ$, is strictly less than this. But the area of $\triangle OPQ$ is of course $\tfrac{1}{2}\sin2\theta$, therefore the area $\theta$ of the circular sector $OPRQ$ is strictly less than $\tfrac{2}{3}\tan\theta + \tfrac{1}{6}\sin2\theta$, as claimed. (Of course we need to double the value, as shown, if we want to estimate $\eta$ rather than $\theta$.) $\square$
That proves the upper bound. The proof of the lower bound is simpler (and easier to "see", because it does not involve any points or lines not shown in the diagram!). The area of $\triangle PRQ$ inscribed in the minor parabolic segment $PRQ$ is $QS{\cdot}RS = \sin\theta(1 - \cos\theta) = \sin\theta - \tfrac{1}{2}\sin2\theta$. By Archimedes's theorem again, the area of the minor parabolic segment $PRQ$ is $\tfrac{4}{3}$ of this value. It is shown below that the minor parabolic segment $PRQ$ is contained within the circular segment $PRQ$. Therefore, the area of the circular segment $PRQ$ is strictly greater than $\tfrac{4}{3}(\sin\theta - \tfrac{1}{2}\sin2\theta)$. Adding the area $\tfrac{1}{2}\sin2\theta$ of $\triangle OPQ$ again, it follows that the area of the circular sector is strictly greater than $\tfrac{4}{3}\sin\theta - \tfrac{1}{6}\sin2\theta$. (Again, double this value to estimate $\eta$ rather than $\theta$.) $\square$
It remains only to prove the two lemmas assumed in the above proof, as well as the "well-known" [translation: I found it in an old schoolbook from 50 years ago!] theorem that the tangent to a parabola at a point $P$ intersects the axis of the parabola at a point whose distance from the vertex of the parabola is the same as that of the foot of the perpendicular from $P$ to the axis. Fortunately, all three of these results are virtually trivial to prove using good old coordinate geometry and school calculus, which I can almost remember:
If the vertex of a parabola is taken as the origin of a Cartesian coordinate system, and the axis of the parabola is taken as the positive $y$-axis, then the unit of length can be chosen so that the equation of the parabola is $y = x^2$. That makes everything really easy.
First, of course, is Archimedes's great quadrature result, which nowadays any schoolchild (standing on the shoulders of giants!) can prove. For all $a > 0$, we have $\int_{-a}^ax^2\,dx = \tfrac{2}{3}a^3$, therefore the area of the parabolic segment below the line $y = a^2$ is $2a^3 - \tfrac{2}{3}a^3 = \tfrac{4}{3}a^3$, which is $\tfrac{4}{3}$ the area of the triangle inscribed in the segment. $\square$
Equally easy (after centuries of progress!) is the theorem about the tangent: the slope of the tangent at $(a, a^2)$ is $2a$, so it intersects the axis of the parabola, i.e. the $y$-axis, at the point $(0, -a^2)$. $\square$
For the lemma of the minor parabolic segment, suppose that a circle with centre inside the parabola and on its axis passes through the vertex of the parabola and also some other point of the parabola, which by symmetry we may take to be $(a, a^2)$ for some $a > 0$. If the radius of the circle is $r > 0$, then its centre is $(0, r)$, and we have $a^2 + (a^2 - r)^2 = r^2$, which simplifies to $a^2 = 2r - 1$. A point $(x, x^2)$ of the parabola other than $(0, 0)$ lies inside the circle if and only if $x^2 + (x^2 - r)^2 < r^2$, which simplifies to $x^2 < 2r - 1 = a^2$, i.e. to $|x| < |a|$. Therefore the arc of the parabola between $(a, a^2)$ and $(-a, a^2)$ lies inside the circle, apart from its point of contact at the origin, i.e. the vertex. $\square$
For the lemma of the major parabolic segment, observe that the slope of the normal to the parabola at $(a, a^2)$ is $-\tfrac{1}{2a}$, so it meets the $y$-axis at $(0, a^2 + \tfrac{1}{2})$, which must therefore be the centre of the circle touching the parabola at $(\pm a, a^2)$. The radius of the circle is $\sqrt{a^2 + \tfrac{1}{4}}$. For all $x$, we have
\begin{align*}
x^2 + \left(x^2 - a^2 - \tfrac{1}{2}\right)^2 - a^2 - \tfrac{1}{4} & =
x^2 + x^4 - (2a^2 + 1)x^2 + a^4 + a^2 + \tfrac{1}{4} - a^2 - \tfrac{1}{4} \\
& = x^4 - 2a^2x^2 + a^4 \\ & = (x^2 - a^2)^2,
\end{align*}
and this is strictly positive except when $x = \pm a$, showing that apart from the two given points of contact, every other point of the parabola lies outside the circle. $\square$
Addendum 1
Here is a computation of $\pi$ to 9 decimal places, using (in 8 iterations, which more than sufficed): 8 square root extractions, 16 long divisions, 17 divisions by single-digit numbers, 25 multiplications by single-digit numbers, and 24 additions or subtractions. It would be perfectly feasible to do this all literally "by hand". I'm not that masochistic, but I did stubbornly stick to using only a cheap non-programmable calculator (Casio fx-85GT+). Here, at the risk of making myself look very silly indeed, is the informal "program" that I have just "executed":
1 Mentally (and on paper) set n = 0
2 1 --> X
3 3sqrt(3)/2 --> A
4 Begin loop:
5 Write X in third column of table
6 Write A in fourth column of table
7 If n > 0, write (4A - M)/3 in fifth column of table
8 If n > 0, write (4A/X + M)/3 in sixth column of table
9 A --> M
10 sqrt(2 + X) --> X
11 2A/X --> A
12 Terminate or pause here if desired (memories aren't volatile);
otherwise, mentally (and on paper) increment n, and return to
the beginning of the loop
The above instructions represent the recursive formulae
\begin{gather*}
2x_0 = 1, \quad A_0 = \frac{3\sqrt{3}}{2}; \\
2x_n = \sqrt{2 + 2x_{n-1}}, \quad A_n = A_{n-1}/x_n \quad (n > 0); \\
B_n = \frac{4A_n -A_{n-1}}{3}, \quad C_n = \frac{2A_n/x_n + A_{n-1}}{3}
\quad (n > 0).
\end{gather*}
$$
\begin{array}{|r||r||c|c|c|c|}
\hline
n & 3\cdot2^{n+1} & 2x_n & A_n & B_n & C_n \\
\hline
\hline
0 & 6 & 1.000000000 & 2.598076211 & - & - \\
1 & 12 & 1.732050808 & 3.000000000 & 3.133974596 & 3.175426481 \\
2 & 24 & 1.931851653 & 3.105828541 & 3.141104722 & 3.143593539 \\
3 & 48 & 1.982889723 & 3.132628613 & 3.141561971 & 3.141716142 \\
4 & 96 & 1.995717846 & 3.139350203 & 3.141590733 & 3.141600348 \\
5 & 192 & 1.998929175 & 3.141031951 & 3.141592534 & 3.141593134 \\
6 & 384 & 1.999732276 & 3.141452472 & 3.141592646 & 3.141592684 \\
7 & 768 & 1.999933068 & 3.141557608 & 3.141592653 & 3.141592655 \\
8 & 1536 & 1.999983267 & 3.141583892 & 3.141592654 & 3.141592654 \\
9 & 3072 & 1.999995817 & 3.141590463 & 3.141592654 & 3.141592654 \\
10 & 6144 & 1.999998954 & 3.141592106 & \bumpeq \pi & \bumpeq \pi \\
\hline
\end{array}
$$
Although $B_n$ and $C_n$ are the bounds calculated by erecting parabolic arcs on the sides of a $3\cdot2^n$-gon, their computation effectively requires the construction of a $3\cdot2^{n+1}$-gon, which is why they appear in row $n$ rather than row $n-1$ of the table.
The entries "$\bumpeq \pi$" in the last row represent where the calculator reached the limit of its internal precision, threw up its hands, and declared that both numbers were exactly $\pi$, poor thing.
Addendum 2
I stated that the area of the major parabolic
segment is $\tfrac{2}{3}$ of the area of the trapezium $PTUQ$, but I
gave no argument for this, other than an anachronistically
"modern" trigonometric calculation, leaving it unclear what
kind of proof Archimedes or Eratosthenes might have come up with.
Here is such a proof:

The area of the
triangle $\triangle QSZ$ is equal to that of the quadrilateral $QSRU$. This
follows from the congruence of the triangles $\triangle OZQ, \triangle OUR$,
upon subtracting the area of the triangle $\triangle OSQ$.
Because $N$ is the midpoint of $SZ$, the area of $\triangle PNQ$ is half that of $\triangle PZQ$, therefore the area of the major parabolic segment $PRQ$ is $\tfrac{2}{3}$ that of $\triangle PZQ$, therefore it is $\tfrac{4}{3}$ that of $\triangle QSZ$, therefore it is $\tfrac{4}{3}$ that of quadrilateral $QSRU$, therefore it is $\tfrac{2}{3}$ that of quadrilateral $PTUQ$. $\square$
I also only proved by trigonometry (and didn't even mention) that
$QR$ bisects $\angle ZQS$ in $\triangle ZQS$. Archimedes and his colleagues
could prove this by drawing a line from $Q$ to the other end of the diameter from $R$. See the new figure. $\square$
Knowing the ratio $QV/OQ$ (in this case $\tfrac{1}{4}$),
our ancient Greek geometers would have been able to calculate
$QS$, and then $RS$, by twice bisecting the given angle $\angle
POQ$. And they could even more easily calculate $RU$. Thus the area of
the circular segment $PRQ$, or rather $\tfrac{3}{2}$ of the area,
has been trapped between the two known polygonal areas $PYXQ$ and
$PTUQ$.