The Wikipedia page Isai linked to basically says it all, but I think it is worth unpacking some of the definitions given there here with a bit more motivation.
To generalize the usual $\mathbb{R}^n$ dot product, what we can do is to look at the properties of that dot product, and then see if we can come up with something in $\mathbb{C}^n$ that has similar properties.
One characterization of the regular dot product is as being a "symmetric positive-definite bilinear form". Let's unpack:
symmetric: $\vec{v} \cdot \vec{w}$ = $\vec{w} \cdot \vec{v}$. This is linked to the notion of the angle between two vectors being the same regardless of order.
positive definite: $\forall \vec{v} \ne \vec{0}, \vec{v} \cdot \vec{v} > 0$. This corresponds to our usual notion of the "size of a vector being a positive real number". Remember that a inner product like the dot product naturally induces a norm
bilinear: linear in both arguments, i.e. $(a \vec{v}) \cdot \vec{w}$ = $a (\vec{v} \cdot \vec{w})$ and $(\vec{v} + \vec{u}) \cdot \vec{w} = (\vec{v} \cdot \vec{w}) + (\vec{u} \cdot \vec{w})$
form: in the context of linear algebra, a form is a (multi-)linear map that has codomain as the underlying field of a vector space, e.g. from $\mathbb{R}^n$ to $\mathbb{R}$, $\mathbb{C}^n$ to $\mathbb{C}$
Note however that the complex are not orderable, so this definition of "form" won't work well with "positive definiteness" for the complex numbers, unless we pick a form that maps $\mathbb{C}^n$ to $\mathbb{R}$
The standard definition of the complex product mentioned by Isai:
$$\vec{v} \cdot \vec{w} = \sum_i v_i\overline{w_i}$$
is one that does what it can to salvage the positive definiteness, but it has to sacrifice some of the other properties in the process:
symmetric: sacrificed, obviously, since $v_i \overline{w_i} \ne w_i \overline{v_i}$ in general.
What is maintained however is $\vec{v} \cdot \vec{w} = \overline{\vec{w} \cdot \vec{v}}$. And we also note that this version is also valid for the real forms, since for real numbers $a = \overline{a}$, so we could use it as a more general version of symmetry that is maintained in both cases.
positive definite: maintained. E.g. if we consider $\mathbb{C}^1$:
$$(a + bi) \cdot (a + bi) = (a + bi)(a - bi) = (aa + -abi + bia -bbii) = a^2 + b^2$$
So we see that this form always maps to positive real numbers, not arbitrary complex numbers, and so it makes sense to talk about positive definiteness.
As mentioned by boojum in the comments, a huge motivation for keeping this property is quantum mechanics, where $\psi \cdot \psi$ is the sum of the probabilities of every possible outcome of an experiment, which we want to always be the real positive number 1.
bilinear: for addition is maintained:
$$\vec{v} \cdot \overline{\vec{w} + \vec{u}} = \vec{v} \cdot \overline{\vec{w}} + \vec{v} \cdot \overline{\vec{u}}$$
but for scalar multiplication, it is maintained only if the scalars are real, otherwise:
$$v_i \overline{(a + bi) w_i} = (a - bi) v_i \overline{w_i} \ne (a + bi) v_i \overline{w_i}$$
We could however cheat here once again as for symmetry, and say that the real multiplication linearity on the second argument should actually be defined as:
$$\vec{v} \cdot a \vec{w} = \overline{a} \vec{v} \cdot \vec{w}$$
which would work on both real and complex cases.
form: maintained obviously
This complex "dot product" is sometimes called a Hermitian form. This specific separate term serves as a way to make it clear that it might not comply with the usual definition of a dot product, if you don't generalize that definition as shown above.
zdotu
does not take the complex conjugate the second operand. – Jellicle Oct 25 '17 at 18:55