Suppose $\,d\,$ is a gcd of $\,x^5,x^6$ in $R.\,$ By the general (universal) definition of the gcd
$\ \ \ c\mid x^5,x^6\! \iff c\mid d.\, $ Taking $c = d\,$ $\rm\color{#0a0}{shows}$ $\,d\mid \color{#c00}{x^5},x^6,\,$ i.e. the gcd is a common divisor.
$x^3\mid x^5,x^6\ \ \Rightarrow\ \ x^3\mid d,\ $ hence $\ d = x^3,\, x^4,\,$ or $\ \color{#c00}{x^5}\, $ (up to unit factors). But none work since
$x^2\mid x^5,x^6\ \ \Rightarrow\ \ \color{#90f}{x^2\mid x^3}\,$ if $\:d=x^3,\ $ $\rm\color{#0a0}{and}$ $\,d=x^4\Rightarrow\, \color{#90f}{x^4\mid x^5},\,$ and $\,d=x^5\Rightarrow\, \color{#90f}{x^5\mid x^6}.\ $
Thus every possibility for $\,d\,$ yields some $\,\color{#90f}{x^i\mid x^{i+1}}$ in $R$ $\,\Rightarrow\, x^{i+1}/x^i = x\in R,\,$ contradiction.
Remark $ $ There are a couple problems in the attempted proof. First, it is easy to show that the elements of $\,\Bbb Q[x^2,x^3]$ are precisely the polynomials $\,f(x)\in \Bbb Q[x]\,$ whose coefficient of $\,x^{1}$ is zero, i.e. $\:x^2\mid f(x)-f(0).\,$ There is no reason given for your assumption that these have the very special form $\,ax^2+bx^3\,$ for $\,a,b\in \Bbb Q\,$ for the both gcd and the Bezout coefficients polynomials.
Second, there is no reason to believe that if the gcd exists then it satisfies a Bezout identity. Indeed, this is proved in $\,\Bbb Q[x]\,$ by using the division algorithm, but that fails dramatically here. We cannot even perform the first step in computing the Bezout identity for $\,\gcd(x^6,x^5)\,$ by the (extended) Euclidean algorithm, i.e. we cannot divide $\,x^6\,$ by $\,x^5\,$ in $R$ to get a smaller degree remainder, since $\,x^6 = x^5 q + r\,\Rightarrow\, r=0\,$ by evaluating at $\,x=0,\,$ so $\,x^6 = x^5 q\Rightarrow\, q = x\in R,\,$ contradiction.